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Polypropylene (PP), also known as polypropene, is a thermoplastic polymer used in a wide variety of applications. It is produced via chain-growth polymerization from the monomer propylene. Polypropylene belongs to the group of polyolefins and is partially crystalline and non-polar.
Polymer morphology is a microscale property that is largely dictated by the amorphous or crystalline portions of the polymer chains and their influence on each other. Microscopy techniques are especially useful in determining these microscale properties, as the domains created by the polymer morphology are large enough to be viewed using modern ...
Crystalline polymers polypropylene and polyethylene display particle strengthening. [28] Plastics are viscoelastic materials meaning that under applied stress, their deformation increases with time (creep). The elastic properties of plastics are therefore distinguished according to the time scale of the testing to short-time behavior (such as ...
The amorphous polyalphaolefins are synthesized by a catalyst system based on a Z-N supported catalyst and an alkyl aluminum co-catalyst. The polymerization process produces a mostly amorphous polymer with low crystallinity. Crystallinity depends on the catalyst system and on the use of co-monomers.
Polyamorphism is also an important area in pharmaceutical science. The amorphous form of a drug typically has much better aqueous solubility (compared to the analogous crystalline form) but the actual local structure in an amorphous pharmaceutical can be different, depending on the method used to form the amorphous phase.
All polymers (amorphous or semi-crystalline) go through glass transitions. The glass-transition temperature ( T g ) is a crucial physical parameter for polymer manufacturing, processing, and use. Below T g , molecular motions are frozen and polymers are brittle and glassy.
In condensed matter physics and materials science, an amorphous solid (or non-crystalline solid) is a solid that lacks the long-range order that is characteristic of a crystal. The terms " glass " and "glassy solid" are sometimes used synonymously with amorphous solid; however, these terms refer specifically to amorphous materials that undergo ...
Amorphous solid: A solid in which there is no far-range order of the positions of the atoms. Crystalline solid: A solid in which atoms, molecules, or ions are packed in regular order. Quasicrystal: A solid in which the positions of the atoms have long-range order, but this is not in a repeating pattern.