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A colloid has a dispersed phase (the suspended particles) and a continuous phase (the medium of suspension). The dispersed phase particles have a diameter of approximately 1 nanometre to 1 micrometre. [2] [3] Some colloids are translucent because of the Tyndall effect, which is the scattering of light by particles in
When a surface is immersed in a solution containing electrolytes, it develops a net surface charge.This is often because of ionic adsorption. Aqueous solutions universally contain positive and negative ions (cations and anions, respectively), which interact with partial charges on the surface, adsorbing to and thus ionizing the surface and creating a net surface charge. [9]
Diagram showing the ionic concentration and potential difference as a function of distance from the charged surface of a particle suspended in a dispersion medium. Zeta potential is the electrical potential at the slipping plane. This plane is the interface which separates mobile fluid from fluid that remains attached to the surface.
The surface energy of a liquid may be measured by stretching a liquid membrane (which increases the surface area and hence the surface energy). In that case, in order to increase the surface area of a mass of liquid by an amount, δA, a quantity of work, γ δA, is needed (where γ is the surface energy density of the liquid).
In 1923, Peter Debye and Erich Hückel reported the first successful theory for the distribution of charges in ionic solutions. [7] The framework of linearized Debye–Hückel theory subsequently was applied to colloidal dispersions by S. Levine and G. P. Dube [8] [9] who found that charged colloidal particles should experience a strong medium-range repulsion and a weaker long-range attraction.
Derjaguin approximation related the force between two spheres (top) and the interaction energy between two plates (bottom). The Derjaguin approximation (or sometimes also referred to as the proximity approximation), named after the Russian scientist Boris Derjaguin, expresses the force profile acting between finite size bodies in terms of the force profile between two planar semi-infinite ...
Particle agglomeration refers to the formation of assemblages in a suspension and represents a mechanism leading to the functional destabilization of colloidal systems. . During this process, particles dispersed in the liquid phase stick to each other, and spontaneously form irregular particle assemblages, flocs, or agglom
Colloids and Surfaces is a peer-reviewed journal of surface science. It was established in 1980. In 1993, it split into two parts Colloids and Surfaces A and Colloids ...