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A colloid has a dispersed phase (the suspended particles) and a continuous phase (the medium of suspension). The dispersed phase particles have a diameter of approximately 1 nanometre to 1 micrometre. [2] [3] Some colloids are translucent because of the Tyndall effect, which is the scattering of light by particles in
In 1923, Peter Debye and Erich Hückel reported the first successful theory for the distribution of charges in ionic solutions. [7] The framework of linearized Debye–Hückel theory subsequently was applied to colloidal dispersions by S. Levine and G. P. Dube [8] [9] who found that charged colloidal particles should experience a strong medium-range repulsion and a weaker long-range attraction.
Colloids and Surfaces is a peer-reviewed journal of surface science. It was established in 1980. In 1993, it split into two parts Colloids and Surfaces A and Colloids ...
It is universally included in text books on colloid chemistry and is still widely applied in modern studies of interparticle forces in colloids. In particular, the Derjaguin approximation is widely used in order to approximate the interaction between curved surfaces from a knowledge of the interaction for planar ones.
In this model, the charge distribution of ions as a function of distance from the metal surface allows Maxwell–Boltzmann statistics to be applied. Thus the electric potential decreases exponentially away from the surface of the fluid bulk. [3] [6] Gouy-Chapman layers may bear special relevance in bioelectrochemistry.
Unlike solutions and colloids, if left undisturbed for a prolonged period of time, the suspended particles will settle out of the mixture. Although suspensions are relatively simple to distinguish from solutions and colloids, it may be difficult to distinguish solutions from colloids since the particles dispersed in the medium may be too small ...
The surface energy of a liquid may be measured by stretching a liquid membrane (which increases the surface area and hence the surface energy). In that case, in order to increase the surface area of a mass of liquid by an amount, δA, a quantity of work, γ δA, is needed (where γ is the surface energy density of the liquid).
In molecular physics, the Hamaker constant (denoted A; named for H. C. Hamaker) is a physical constant that can be defined for a van der Waals (vdW) body–body interaction: