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Polyhedral representation of spinel MgAl 2 O 4. Spinel (/ s p ɪ ˈ n ɛ l, ˈ s p ɪ n əl / [7]) is the magnesium/aluminium member of the larger spinel group of minerals. It has the formula MgAl 2 O 4 in the cubic crystal system. Its name comes from the Latin word spinella, a diminutive form of spine, in reference to its pointed crystals. [5]
Inverse spinel structures have a different cation distribution in that all of the A cations and half of the B cations occupy octahedral sites, while the other half of the B cations occupy tetrahedral sites. An example of an inverse spinel is Fe 3 O 4, if the Fe 2+ (A 2+) ions are d 6 high-spin and the Fe 3+ (B 3+) ions are d 5 high-spin.
Sapphire (gem corundum of any color except red, especially blue varieties) Sard (a variety of chalcedony/quartz) Satinspar (a variety of gypsum) Selenite (a variety of gypsum) Simetite (a variety of amber) Smoky quartz (a brown or black variety of quartz) Soda niter (synonym of nitratine) Spectrolite (a variety of labradorite) Spessartite ...
[4] [5] As such, it is the only gemstone to have been initially identified from a faceted stone. Most pieces of the gem, prior to Taaffe, had been misidentified as spinel. For many years afterwards, it was known only in a few samples, and it is still one of the rarest gemstone minerals in the world. [6]
Samarian Spinel, the world's largest spinel; Menshikov Ruby, the world's second largest spinel set on top of the Great Imperial Crown of Russia; Timur Ruby, believed to be a ruby until 1851, hence its name; Black Prince's Ruby, the famous spinel mounted on the Imperial State Crown of the United Kingdom
The gemstone at the front of the Imperial State Crown. The Black Prince's Ruby is a large, irregular cabochon red spinel weighing 170 carats (34 g) set in the cross pattée above the Cullinan II diamond at the front of the Imperial State Crown of the United Kingdom.
The mineral ceylonite has the chemical composition of (Mg, Fe 2+) Al 2 O 4, putting it into a group of minerals known as the spinel group, or the oxide spinels. The oxide spinels have a formula of the model [A][B] 2 O 4; where [A] is commonly Fe 2+, Mg 2+, or Mn 2+, and [B] is Fe 3+, Al 3+, or Cr 3+. It is an iron-rich variety of the spinel ...
Galaxite is the manganese (Mn) rich endmember of the aluminium (Al) series of the spinel group. Divalent iron (Fe) and magnesium (Mg) readily substitute for the manganese in the crystal structure. Trivalent iron may also substitute for the aluminium. Thus, reflecting most natural samples, the formula may be better represented as (Mn,Fe 2+,Mg ...