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Brunauer, Emmett and Teller's model of multilayer adsorption is a random distribution of molecules on the material surface. Adsorption is the adhesion [1] of atoms, ions or molecules from a gas, liquid or dissolved solid to a surface. [2] This process creates a film of the adsorbate on the surface of the adsorbent.
The amount of adsorbed gas depends on pressure, temperature and adsorbent type. Since this adsorption process is exothermic, an increase in pressure or a decrease in temperature enhances the efficiency of the adsorption process. It is possible to mix the ANG and CNG technology to reach an increased capacity of natural gas storage.
gas molecules only interact with adjacent layers; and; the Langmuir theory can be applied to each layer. the enthalpy of adsorption for the first layer is constant and greater than the second (and higher). the enthalpy of adsorption for the second (and higher) layers is the same as the enthalpy of liquefaction. The resulting BET equation is
Adsorption is an essential step in heterogeneous catalysis. Adsorption is the process by which a gas (or solution) phase molecule (the adsorbate) binds to solid (or liquid) surface atoms (the adsorbent). The reverse of adsorption is desorption, the adsorbate splitting from adsorbent. In a reaction facilitated by heterogeneous catalysis, the ...
The adsorption sites (heavy dots) are equivalent and can have unit occupancy. Also, the adsorbates are immobile on the surface. The Langmuir adsorption model explains adsorption by assuming an adsorbate behaves as an ideal gas at isothermal conditions. According to the model, adsorption and desorption are reversible processes.
Gas–liquid absorption (a) and liquid–solid adsorption (b) mechanism. Blue spheres are solute molecules. Sorption is a physical and chemical process by which one substance becomes attached to another. Specific cases of sorption are treated in the following articles: Absorption
Pressure swing adsorption (PSA) is a technique used to separate some gas species from a mixture of gases (typically air) under pressure according to the species' molecular characteristics and affinity for an adsorbent material.
Gas separation can refer to any of a number of techniques used to separate gases, either to give multiple products or to purify a single product. Swing adsorption techniques [ edit ]