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Pourbaix diagram of iron. [1] The Y axis corresponds to voltage potential. In electrochemistry, and more generally in solution chemistry, a Pourbaix diagram, also known as a potential/pH diagram, E H –pH diagram or a pE/pH diagram, is a plot of possible thermodynamically stable phases (i.e., at chemical equilibrium) of an aqueous electrochemical system.
To use potentiometric (e.m.f.) measurements in monitoring the + concentration in place of readings, one can trivially set [+] = and apply the same equations as above, where is the offset correction /, and is a slope correction / (1/59.2 pH units/mV at 25°C), such that replaces .
Some simple systems are amenable to spreadsheet calculations. [4] [14] A large number of general-purpose computer programs for equilibrium constant calculation have been published. See [15] for a bibliography. The most frequently used programs are: Potentiometric data: Hyperquad, BEST [16] PSEQUAD, [17] ReactLab pH PRO
A calibration curve plot showing limit of detection (LOD), limit of quantification (LOQ), dynamic range, and limit of linearity (LOL).. In analytical chemistry, a calibration curve, also known as a standard curve, is a general method for determining the concentration of a substance in an unknown sample by comparing the unknown to a set of standard samples of known concentration. [1]
The equation for head loss in pipes, also referred to as slope, S, expressed in "feet per foot of length" vs. in 'psi per foot of length' as described above, with the inside pipe diameter, d, being entered in feet vs. inches, and the flow rate, Q, being entered in cubic feet per second, cfs, vs. gallons per minute, gpm, appears very similar.
The Penman equation describes evaporation (E) from an open water surface, and was developed by Howard Penman in 1948. Penman's equation requires daily mean temperature, wind speed, air pressure, and solar radiation to predict E. Simpler Hydrometeorological equations continue to be used where obtaining such data is impractical, to give comparable results within specific contexts, e.g. humid vs ...
It uses a combination of the energy, momentum, and continuity equations to determine water depth with a given a friction slope (), channel slope (), channel geometry, and also a given flow rate. In practice, this technique is widely used through the computer program HEC-RAS , developed by the US Army Corps of Engineers Hydrologic Engineering ...
Allen Hazen derived an empirical formula for approximating hydraulic conductivity from grain-size analyses: = where Hazen's empirical coefficient, which takes a value between 0.0 and 1.5 (depending on literature), with an average value of 1.0. A.F. Salarashayeri & M. Siosemarde indicate C is usually between 1.0 and 1.5, with D in mm and K in cm/s.