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The term subcooling (also called undercooling) refers to the intentional process of cooling a liquid below its normal boiling point. For example, water boils at 373 K; at room temperature (293 K) liquid water is termed "subcooled". Subcooling is a common stage in refrigeration cycles and steam turbine cycles.
The heat content of an ideal gas is independent of pressure (or volume), but the heat content of real gases varies with pressure, hence the need to define the state for the gas (real or ideal) and the pressure. Note that for some thermodynamic databases such as for steam, the reference temperature is 273.15 K (0 °C).
Data in the table above is given for water–steam equilibria at various temperatures over the entire temperature range at which liquid water can exist. Pressure of the equilibrium is given in the second column in kPa. The third column is the heat content of each gram of the liquid phase relative to water at 0 °C.
The compressed fluid region is located to the left of the blue line (the liquid-vapor phase boundary). The international pictogram for compressed gases. A compressed fluid (also called a compressed or unsaturated liquid, [1] subcooled fluid or liquid) is a fluid under mechanical or thermodynamic conditions that force it to be a liquid. [2]
For gases, departure from 3 R per mole of atoms is generally due to two factors: (1) failure of the higher quantum-energy-spaced vibration modes in gas molecules to be excited at room temperature, and (2) loss of potential energy degree of freedom for small gas molecules, simply because most of their atoms are not bonded maximally in space to ...
Steam engines use water vapor to push pistons or turbines, and that movement creates work. The quantitatively described steam quality (steam dryness) is the proportion of saturated steam in a saturated water/steam mixture. In other words, a steam quality of 0 indicates 100% liquid, while a steam quality of 1 (or 100%) indicates 100% steam.
The Mollier enthalpy–entropy diagram for water and steam. The "dryness fraction", x , gives the fraction by mass of gaseous water in the wet region, the remainder being droplets of liquid. An enthalpy–entropy chart , also known as the H – S chart or Mollier diagram , plots the total heat against entropy, [ 1 ] describing the enthalpy of a ...
The regenerative Rankine cycle is so named because after emerging from the condenser (possibly as a subcooled liquid) the working fluid is heated by steam tapped from the hot portion of the cycle. On the diagram shown, the fluid at 2 is mixed with the fluid at 4 (both at the same pressure) to end up with the saturated liquid at 7.