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  2. Curing (chemistry) - Wikipedia

    en.wikipedia.org/wiki/Curing_(chemistry)

    Curing is a chemical process employed in polymer chemistry and process engineering that produces the toughening or hardening of a polymer material by cross-linking of polymer chains. [1] Even if it is strongly associated with the production of thermosetting polymers , the term "curing" can be used for all the processes where a solid product is ...

  3. Bulk polymerization - Wikipedia

    en.wikipedia.org/wiki/Bulk_polymerization

    There is no agitation in this type of bulk polymerization. This is often used to synthesize cross-linked and thermosetting polymers. Due to dormant nature of the system, the Trommsdorff effect is significantly present, which in turn leads to longer chains and tougher material.

  4. Cross-link - Wikipedia

    en.wikipedia.org/wiki/Cross-link

    In vulcanization, sulfur is the cross-linking agent. Its introduction changes rubber to a more rigid, durable material associated with car and bike tires. This process is often called sulfur curing. In most cases, cross-linking is irreversible, and the resulting thermosetting material will degrade or burn if heated, without melting.

  5. Exothermic reaction - Wikipedia

    en.wikipedia.org/wiki/Exothermic_reaction

    An energy profile of an exothermic reaction. In an exothermic reaction, by definition, the enthalpy change has a negative value: ΔH = H products - H reactants < 0. where a larger value (the higher energy of the reactants) is subtracted from a smaller value (the lower energy of the products). For example, when hydrogen burns: 2H 2 (g) + O 2 (g ...

  6. Ellingham diagram - Wikipedia

    en.wikipedia.org/wiki/Ellingham_diagram

    For comparison of different reactions, all values of ΔG refer to the reaction of the same quantity of oxygen, chosen as one mole O (1 ⁄ 2 mol O 2) by some authors [2] and one mole O 2 by others. [3] The diagram shown refers to 1 mole O 2, so that e.g. the line for the oxidation of chromium shows ΔG for the reaction 4 ⁄ 3 Cr(s) + O 2 (g ...

  7. Thermal decomposition - Wikipedia

    en.wikipedia.org/wiki/Thermal_decomposition

    When water is heated to well over 2,000 °C (2,270 K; 3,630 °F), a small percentage of it will decompose into OH, monatomic oxygen, monatomic hydrogen, O 2, and H 2. [3] The compound with the highest known decomposition temperature is carbon monoxide at ≈3870 °C (≈7000 °F). [citation needed]

  8. Hammond's postulate - Wikipedia

    en.wikipedia.org/wiki/Hammond's_postulate

    George Hammond developed the postulate during his professorship at Iowa State University. Hammond's postulate (or alternatively the Hammond–Leffler postulate), is a hypothesis in physical organic chemistry which describes the geometric structure of the transition state in an organic chemical reaction. [1]

  9. Enthalpy change of solution - Wikipedia

    en.wikipedia.org/wiki/Enthalpy_change_of_solution

    The energy released by the solvation of the ammonium ions and nitrate ions is less than the energy absorbed in breaking up the ammonium nitrate ionic lattice and the attractions between water molecules. Dissolving potassium hydroxide is exothermic, as more energy is released during solvation than is used in breaking up the solute and solvent.