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Diamonds are carbon crystals that form under high temperatures and extreme pressures such as deep within the Earth. At surface air pressure (one atmosphere), diamonds are not as stable as graphite, and so the decay of diamond is thermodynamically favorable (δH = −2 kJ/mol). [22]
Rapid conversion of graphite to diamond requires pressures well above the equilibrium line: at 2000 K, a pressure of 35 GPa is needed. [10] Above the graphite–diamond–liquid carbon triple point, the melting point of diamond increases slowly with increasing pressure; but at pressures of hundreds of GPa, it decreases. [12]
Diamond is an excellent electrical insulator, but graphite is an excellent conductor. Diamond is an excellent thermal conductor, but some forms of graphite are used for thermal insulation (for example heat shields and firebreaks). At standard temperature and pressure, graphite is the thermodynamically stable form. Thus diamonds do not exist ...
Diamond and graphite materials and structure. Diamond is an allotrope of carbon where the atoms are arranged in a modified version of face-centered cubic (fcc) structure known as "diamond cubic". It is known for its hardness (see table above) and incompressibility and is targeted for some potential optical and electrical applications.
Graphite-containing refractories are sometimes also recycled, but often are not due to their low graphite content: the largest-volume items, such as carbon-magnesite bricks that contain only 15–25% graphite, usually contain too little graphite to be worthwhile to recycle. However, some recycled carbon–magnesite brick is used as the basis ...
Diamond and graphite are two allotropes of carbon: pure forms of the same element that differ in crystalline structure.. Allotropy or allotropism (from Ancient Greek ἄλλος (allos) 'other' and τρόπος (tropos) 'manner, form') is the property of some chemical elements to exist in two or more different forms, in the same physical state, known as allotropes of the elements.
In mineralogy, amorphous carbon is the name used for coal, carbide-derived carbon, and other impure forms of carbon that are neither graphite nor diamond. In a crystallographic sense, however, the materials are not truly amorphous but rather polycrystalline materials of graphite or diamond [2] within an amorphous carbon matrix. Commercial ...
In very small minerals, surface energy is important and diamonds are more stable than graphite because the diamond structure is more compact. The crossover in stability is at between 1 and 5 nm. At even smaller sizes, a variety of other forms of carbon such as fullerenes can be found, as well as diamond cores wrapped in fullerenes. [3]