Search results
Results from the WOW.Com Content Network
Polarizability. Polarizability usually refers to the tendency of matter, when subjected to an electric field, to acquire an electric dipole moment in proportion to that applied field. It is a property of particles with an electric charge. When subject to an electric field, the negatively charged electrons and positively charged atomic nuclei ...
v. t. e. In classical electromagnetism, polarization density (or electric polarization, or simply polarization) is the vector field that expresses the volumetric density of permanent or induced electric dipole moments in a dielectric material. When a dielectric is placed in an external electric field, its molecules gain electric dipole moment ...
In electromagnetism, the Clausius–Mossotti relation, named for O. F. Mossotti and Rudolf Clausius, expresses the dielectric constant (relative permittivity, εr) of a material in terms of the atomic polarizability, α, of the material's constituent atoms and/or molecules, or a homogeneous mixture thereof. It is equivalent to the Lorentz ...
Electric susceptibility. In electricity (electromagnetism), the electric susceptibility ( ; Latin: susceptibilis "receptive") is a dimensionless proportionality constant that indicates the degree of polarization of a dielectric material in response to an applied electric field. The greater the electric susceptibility, the greater the ability of ...
When the atomic polarizability is quoted in units of volume such as Å 3, as is often the case, it is equal to the van der Waals volume. However, the term "atomic polarizability" is preferred as polarizability is a precisely defined (and measurable) physical quantity , whereas "van der Waals volume" can have any number of definitions depending ...
Molar refractivity, [1] , is a measure of the total polarizability of a mole of a substance and is dependent on the temperature, the index of refraction, and the pressure. The molar refractivity is defined as. where is the Avogadro constant and is the mean polarizability of a molecule. Substituting the molar refractivity into the Lorentz-Lorenz ...
Atomic units. The atomic units are a system of natural units of measurement that is especially convenient for calculations in atomic physics and related scientific fields, such as computational chemistry and atomic spectroscopy. They were originally suggested and named by the physicist Douglas Hartree. [1]
Hyperpolarizability. The hyperpolarizability, a nonlinear-optical property of a molecule, is the second order electric susceptibility per unit volume. [1] The hyperpolarizability can be calculated using quantum chemical calculations developed in several software packages. [2][3][4] See nonlinear optics.