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Fractional crystallization in silicate melts is complex compared to crystallization in chemical systems at constant pressure and composition, because changes in pressure and composition can have dramatic effects on magma evolution. Addition and loss of water, carbon dioxide, and oxygen are among the compositional changes that must be considered ...
One of the factors that can initiate magma eruption is phase separation of the liquid and crystal components of the crystal mush. As the magma develops over time and the crystal content of the magma increases, phase separation is taking place and the liquid phase of the magma is pushed up, driven by its buoyancy as a result of its lower density.
Magma exists in three main forms that vary in composition. [3] When magma crystallizes within the crust, it forms an extrusive igneous rock. Dependent on the composition of the magma, it may form either rhyolite, andesite, or basalt. [3] Volatiles, particularly water and carbon dioxide, significantly impact the behavior of each form of magma ...
Fresh magma changes the composition of the melt, changing the chemistry of the phases which are being precipitated. For instance, plagioclase conforms to the liquid line of descent by forming initial anorthite which, if removed, changes the equilibrium mineral composition to oligoclase or albite. Replenishment of the magma can see this trend ...
At the bottom of the magma reservoir, a cumulate rock forms. Cumulate rocks are the typical product of precipitation of solid crystals from a fractionating magma chamber. These accumulations typically occur on the floor of the magma chamber, although they are possible on the roofs if anorthite plagioclase is able to float free of a denser mafic ...
The change of rock composition most responsible for the creation of magma is the addition of water. Water lowers the solidus temperature of rocks at a given pressure. For example, at a depth of about 100 kilometres, peridotite begins to melt near 800 °C in the presence of excess water, but near or above about 1,500 °C in the absence of water ...
As a magma changes, parts of it may separate from the main body of magma. Two liquids that will not mix are called immiscible; oil and water are an example. In magmas, sulfides may separate and sink below the silicate-rich part of the intrusion or be injected into the rock surrounding it. These deposits are found in mafic and ultramafic rocks.
[17] [3] The residual magma undergoes phase separation into a melt phase and a hydrous fluid phase saturated with silica, alkalis, and other elements. [8] [18] Such phase separation requires formation from a wet magma, rich enough in water to saturate before more than two-thirds of the magma is crystallized. Otherwise, the separation of the ...