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Volcanogenic massive sulfide ore deposits, also known as VMS ore deposits, are a type of metal sulfide ore deposit, mainly copper-zinc which are associated with and produced by volcanic-associated hydrothermal events in submarine environments. [2] [3] [4] These deposits are also sometimes called volcanic-hosted massive sulfide (VHMS) deposits
Metal mines may generate highly acidic discharges where the ore is a sulfide mineral or is associated with pyrite. In these cases the predominant metal ion may not be iron but rather zinc, copper, or nickel. The most commonly mined ore of copper, chalcopyrite, is itself a copper
Upon exposure to oxygen (O 2) and water (H 2 O), metal sulfides undergo oxidation to produce metal-rich acidic effluent. If the pH is low enough to overcome the natural buffering capacity of the surrounding rocks (‘calcium carbonate equivalent’ or ‘acid neutralising capacity’), the surrounding area may become acidic, as well as contaminated with high levels of heavy metals.
Massive sulfide deposits are ore deposits that have significant stratiform ore bodies consisting mainly of sulfide minerals.Most massive sulfide ore deposits have other portions that are not massive, including stringer or feeder zones beneath the massive parts that mostly consist of crosscutting veins and veinlets of sulfides in a matrix of pervasively altered host rock and gangue.
In an ideal exhalative model, hot dense brines flow to depressed areas of the ocean topography where they mix with cooler, less dense, sea water, causing the dissolved metal and sulfur in the brine to precipitate from solution as a solid metal sulfide ore, deposited as layers of sulfide sediment. [1]
A sulfide deposit is an ore body or rock containing a great deal of sulfide minerals. Articles on this topic include: Seafloor massive sulfide deposits; Sedimentary exhalative deposits; Volcanogenic massive sulfide ore deposit; Massive sulfide deposits
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Based on the extremely low K sp values for heavy metal sulfides, if [SEM]/[AVS] is less than 1 ([SEM < [AVS]), then all the extractable metals in the sediment should be in their solid sulfide form and non-bioavailable; above this value, the pool of sulfide is "exhausted" and heavy metals are more likely to be present in the sediment pore water ...
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