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The physical condition of a thermodynamic system at a given time is described by its state, which can be specified by the values of a set of thermodynamic state variables. A thermodynamic system is in thermodynamic equilibrium when there are no macroscopically apparent flows of matter or energy within it or between it and other systems. [1]
Biological thermodynamics (Thermodynamics of biological systems) is a science that explains the nature and general laws of thermodynamic processes occurring in living organisms as nonequilibrium thermodynamic systems that convert the energy of the Sun and food into other types of energy. The nonequilibrium thermodynamic state of living ...
Systems do not contain work, but can perform work, and likewise, in formal thermodynamics, systems do not contain heat, but can transfer heat. Informally, however, a difference in the energy of a system that occurs solely because of a difference in its temperature is commonly called heat , and the energy that flows across a boundary as a result ...
For systems that are initially far from thermodynamic equilibrium, though several have been proposed, there is known no general physical principle that determines the rates of approach to thermodynamic equilibrium, and thermodynamics does not deal with such rates.
[1] [2] [3] The second law of thermodynamics establishes the concept of entropy as a physical property of a thermodynamic system. It predicts whether processes are forbidden despite obeying the requirement of conservation of energy as expressed in the first law of thermodynamics and provides necessary criteria for spontaneous processes. For ...
For example, when a machine (not a part of the system) lifts a system upwards, some energy is transferred from the machine to the system. The system's energy increases as work is done on the system and in this particular case, the energy increase of the system is manifested as an increase in the system's gravitational potential energy. Work ...
If the system is divided by a wall that is permeable to heat or to matter, the temperature of each subsystem is identical. Additionally, the boiling temperature of a substance is an intensive property. For example, the boiling temperature of water is 100 °C at a pressure of one atmosphere, regardless of the quantity of water remaining as liquid.
Thermodynamic cycles may be used to model real devices and systems, typically by making a series of assumptions to reduce the problem to a more manageable form. [2] For example, as shown in the figure, devices such a gas turbine or jet engine can be modeled as a Brayton cycle. The actual device is made up of a series of stages, each of which is ...
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