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Enthalpy (/ ˈ ɛ n θ əl p i / ⓘ) is the sum of a thermodynamic system's internal energy and the product of its pressure and volume. [1] It is a state function in thermodynamics used in many measurements in chemical, biological, and physical systems at a constant external pressure, which is conveniently provided by the large ambient atmosphere.
When a substance or compound is combined with any other substance or compound, the enthalpy of mixing is the consequence of the new interactions between the two substances or compounds. [1] This enthalpy, if released exothermically, can in an extreme case cause an explosion. Enthalpy of mixing can often be ignored in calculations for mixtures ...
Standard enthalpy of combustion is the enthalpy change when one mole of an organic compound reacts with molecular oxygen (O 2) to form carbon dioxide and liquid water. For example, the standard enthalpy of combustion of ethane gas refers to the reaction C 2 H 6 (g) + (7/2) O 2 (g) → 2 CO 2 (g) + 3 H 2 O (l).
For many substances, the formation reaction may be considered as the sum of a number of simpler reactions, either real or fictitious. The enthalpy of reaction can then be analyzed by applying Hess' law, which states that the sum of the enthalpy changes for a number of individual reaction steps equals the enthalpy change of the overall reaction.
, or the change in enthalpy of a reaction, has the same value of as in a thermochemical equation; however, is measured in units of kJ/mol, meaning that it is the enthalpy change per moles of any particular substance in an equation.
In thermochemistry, the heat of dilution, or enthalpy of dilution, refers to the enthalpy change associated with the dilution process of a component in a solution at a constant pressure. If the initial state of the component is a pure liquid (presuming the solution is liquid), the dilution process is equal to its dissolution process and the ...
It is measured as a unit of energy per unit mass or volume of substance. The HHV is determined by bringing all the products of combustion back to the original pre-combustion temperature, including condensing any vapor produced. Such measurements often use a standard temperature of 25 °C (77 °F; 298 K) [citation needed].
The above derivation uses the first and second laws of thermodynamics. The first law of thermodynamics is essentially a definition of heat, i.e. heat is the change in the internal energy of a system that is not caused by a change of the external parameters of the system.