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The two carbon atoms in the ring fusion match [cR3] and the other carbons match [cR2] in the OpenEye implementation of SMARTS. Used without a number, R specifies an atom in a ring in both implementations, for example [CR] (aliphatic carbon atom in ring). Lower case r specifies the size of the smallest ring of which the atom is a member.
The carbon–carbon single bond is a sigma bond and is formed between one hybridized orbital from each of the carbon atoms. In ethane, the orbitals are sp 3-hybridized orbitals, but single bonds formed between carbon atoms with other hybridizations do occur (e.g. sp 2 to sp 2). In fact, the carbon atoms in the single bond need not be of the ...
These numbers are arranged in descending order and are separated by periods. For example, the carbon frame of norbornane contains a total of 7 atoms, hence the root name heptane. This molecule has two paths of 2 carbon atoms and a third path of 1 carbon atom between the two bridgehead carbons, so the brackets are filled in descending order: [2. ...
The bond order itself is the number of electron pairs (covalent bonds) between two atoms. [2] For example, in diatomic nitrogen N≡N, the bond order between the two nitrogen atoms is 3 (triple bond). In acetylene H–C≡C–H, the bond order between the two carbon atoms is also 3, and the C–H bond order is 1 (single bond).
In chemistry, isovalent or second order hybridization is an extension of orbital hybridization, the mixing of atomic orbitals into hybrid orbitals which can form chemical bonds, to include fractional numbers of atomic orbitals of each type (s, p, d). It allows for a quantitative depiction of bond formation when the molecular geometry deviates ...
The isopropenyl group has priority 1 (carbon atoms only), and for the two remaining carbon atoms, priority is decided with the carbon atoms two bonds removed from the stereocenter, one part of the keto group (O, O, C, priority number 2) and one part of an alkene (C, C, H, priority number 3).
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SQL includes operators and functions for calculating values on stored values. SQL allows the use of expressions in the select list to project data, as in the following example, which returns a list of books that cost more than 100.00 with an additional sales_tax column containing a sales tax figure calculated at 6% of the price.