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  2. Molecular orbital diagram - Wikipedia

    en.wikipedia.org/wiki/Molecular_orbital_diagram

    Carbon and each oxygen atom will have a 2s atomic orbital and a 2p atomic orbital, where the p orbital is divided into p x, p y, and p z. With these derived atomic orbitals, symmetry labels are deduced with respect to rotation about the principal axis which generates a phase change, pi bond ( π ) [ 26 ] or generates no phase change, known as a ...

  3. Chemical bonding of water - Wikipedia

    en.wikipedia.org/wiki/Chemical_bonding_of_water

    In the simple MO diagram of H 2 O, the 2s orbital of oxygen is mixed with the premixed hydrogen orbitals, forming a new bonding (2a 1) and antibonding orbital (4a 1). Similarly, the 2p orbital (b 1) and the other premixed hydrogen 1s orbitals (b 1) are mixed to make bonding orbital 1b 1 and antibonding orbital 2b 1. The two remaining 2p ...

  4. Molecular orbital - Wikipedia

    en.wikipedia.org/wiki/Molecular_orbital

    The orbital wave functions are positive in the red regions and negative in the blue. The right column shows virtual MO's which are empty in the ground state, but may be occupied in excited states. In chemistry, a molecular orbital (/ ɒr b ə d l /) is a mathematical function describing the location and wave-like behavior of an electron in a ...

  5. Lewis structure - Wikipedia

    en.wikipedia.org/wiki/Lewis_structure

    Another shorthand structural diagram is the skeletal formula (also known as a bond-line formula or carbon skeleton diagram). In a skeletal formula, carbon atoms are not signified by the symbol C but by the vertices of the lines. Hydrogen atoms bonded to carbon are not shown—they can be inferred by counting the number of bonds to a particular ...

  6. Bond order - Wikipedia

    en.wikipedia.org/wiki/Bond_order

    In diatomic oxygen O=O the bond order is 2 (double bond). In ethylene H 2 C=CH 2 the bond order between the two carbon atoms is also 2. The bond order between carbon and oxygen in carbon dioxide O=C=O is also 2. In phosgene O=CCl 2, the bond order between carbon and oxygen is 2, and between carbon and chlorine is 1.

  7. Localized molecular orbitals - Wikipedia

    en.wikipedia.org/wiki/Localized_molecular_orbitals

    For instance, the lone pairs of water are usually treated as two equivalent sp x hybrid orbitals, while the corresponding "nonbonding" orbitals of carbenes are generally treated as a filled σ(out) orbital and an unfilled pure p orbital, even though the lone pairs of water could be described analogously by filled σ(out) and p orbitals (for ...

  8. File:Valence orbitals of oxygen atom and dioxygen molecule ...

    en.wikipedia.org/wiki/File:Valence_orbitals_of...

    Date/Time Thumbnail Dimensions User Comment; current: 22:16, 7 January 2015: 430 × 648 (58 KB): Rjlanc: defining z as bond direction with x and y for pi orbitals

  9. Linnett double-quartet theory - Wikipedia

    en.wikipedia.org/wiki/Linnett_Double-Quartet_Theory

    The dot-and-cross diagram for molecular oxygen in the ground state. The oxygen nuclei are as indicated and the electrons are denoted by either dots or crosses, depending on their relative spins. The above three-dimensional LDQ structures are useful for visualising the molecular structures, but they can be laborious to construct.