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The Si(100)/H surface does not perturb the electronic properties of graphene, whereas the interaction between the clean Si(100) surface and graphene changes the electronic states of graphene significantly. This effect results from the covalent bonding between C and surface Si atoms, modifying the π-orbital network of the graphene layer.
The electronic properties of graphene are significantly influenced by the supporting substrate. [59] [60] The Si(100)/H surface does not perturb graphene's electronic properties, whereas the interaction between it and the clean Si(100) surface changes its electronic states significantly. This effect results from the covalent bonding between C ...
In 2015 a coiled form of graphene was discovered in graphitic carbon (coal). The spiraling effect is produced by defects in the material's hexagonal grid that causes it to spiral along its edge, mimicking a Riemann surface, with the graphene surface approximately perpendicular to the axis. When voltage is applied to such a coil, current flows ...
Doped graphene layers have also shown the similar surface plasmon effects to that of metallic thin films. [7] [8] Through the engineering of metallic substrates or nanoparticles (e.g., gold, silver and copper) with graphene, the plasmonic properties of the hybrid structures could be tuned for improving the optoelectronic device performances.
Graphene oxide flakes in polymers display enhanced photo-conducting properties. [10] Graphene is normally hydrophobic and impermeable to all gases and liquids (vacuum-tight). However, when formed into graphene oxide-based capillary membrane, both liquid water and water vapor flow through as quickly as if the membrane was not present. [11]
Typical examples include graphene, topological insulators, bismuth antimony thin films and some other novel nanomaterials, [1] [4] [5] in which the electronic energy and momentum have a linear dispersion relation such that the electronic band structure near the Fermi level takes the shape of an upper conical surface for the electrons and a ...
The bilayer graphene shows a specific surface area of 1628 m 2 /g, a pore size ranging from 2 to 7 nm and a total pore volume of 2.0 cm 3 /g. [ 30 ] Using bilayer graphene as cathode material for a lithium sulfur battery yielded reversible capacities of 1034 and 734 mA h/g at discharge rates of 5 and 10 C, respectively.
With GW calculation, the properties of graphene-based materials are accurately investigated, including graphene nanoribbons, [44] edge and surface functionalized armchair graphene nanoribbons [45] and scaling properties in armchair graphene nanoribbons.
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