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Sulfurous acid is commonly known to not exist in its free state, and due to this, it is stated in textbooks that it cannot be isolated in the water-free form. [4] However, the molecule has been detected in the gas phase in 1988 by the dissociative ionization of diethyl sulfite. [5]
The sulfoxylate anion (SO 2− 2) The thiosulfate anion (S 2 O 2− 3) Sodium thiosulfate, a salt containing the thiosulfate anion; S 2 O 2− 2, a reported sulfur oxyanion. However salts containing S 2 O 2− 2 and HS 2 O − 2 are not well characterized; they would be conjugate bases derived from the parent thiosulfurous acid (H 2 S 2 O 2 ...
العربية; Azərbaycanca; বাংলা; Беларуская; Беларуская (тарашкевіца) Български; Bosanski; Català; Чӑвашла
This reaction is useful for the separation and purification of aldehydes. [7] The bisulfite adducts are charged and so are more soluble in polar solvents. The reaction can be reversed in base or strong acid. [8] Examples of such procedures are described for benzaldehyde, [9] 2-tetralone, [10] citral, [11] the ethyl ester of pyruvic acid [12 ...
7 and trisulfate, S 3 O 2− 10: Pure disulfuric acid melts at 36 °C. Present in fuming sulfuric acid, oleum. Examples known for n = 1 and n = 2. Peroxymonosulfuric acid: H 2 SO 5 +6 Peroxomonosulfate, OOSO 2− 3 "Caro's acid", a solid melting at 45 °C Peroxydisulfuric acid: H 2 S 2 O 8 +6 Peroxydisulfate, O 3 SOOSO 2− 3 "Marshall's acid ...
The nomenclature for these molecules is not entirely standardized, and a wide variety of IUPAC-acceptable names are possible. For substances with the −OSOH group, one can use suffixes ‑oxysulfanol (preferred), ‑hydrogen sulfoxylate, or ‑oxysulfenic acid; or prefixes hydroxysulfanyloxy- (preferred) or sulfenooxy-.
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
In solution the fluorosulfate anion is completely ionised. The volume of the ions is 47.8 cm 3 /mol. [ 3 ] Most metal ions, and quaternary ammonium ions, can form fluorosulfate salts. [ 3 ] Different ways to make these salts include treating a metal chloride with anhydrous fluorosulfuric acid, which releases hydrogen chloride gas.