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The reaction has been the subject of several literature reviews. [1] [2] [3] The Nef reaction: 1. Salt of a nitroalkane 3. Ketone 4. Nitrous oxide. The reaction was reported in 1894 by the chemist John Ulric Nef, [4] who treated the sodium salt of nitroethane with sulfuric acid resulting in an 85–89% yield of nitrous oxide and at least 70% ...
Nitroethane is produced industrially by treating propane with nitric acid at 350–450 °C. This exothermic reaction produces four industrially significant nitroalkanes: nitromethane, nitroethane, 1-nitropropane, and 2-nitropropane. The reaction involves free radicals, such as CH 3 CH 2 CH 2 O., which arise via homolysis of the corresponding ...
The oxygen content of nitromethane enables it to burn with much less atmospheric oxygen than conventional fuels. [15] During nitromethane combustion, nitric oxide (NO) is one of the major emission products along with CO 2 and H 2 O. [ 16 ] Nitric oxide contributes to air pollution, acid rain, and ozone layer depletion.
The reaction produces fragments from the parent alkane, creating a diverse mixture of products; for instance, nitromethane, nitroethane, 1-nitropropane, and 2-nitropropane are produced by treating propane with nitric acid in the gas phase (e.g. 350–450 °C and 8–12 atm).
The figure below illustrates one of the commonly accepted models for stereoselection without any modification to the Henry reaction. In this model, stereoselectivity is governed by the size of the R groups in the model (such as a carbon chain), as well as by a transition state that minimizes dipole by orienting the nitro group and carbonyl oxygen anti each other (on opposite sides of the ...
Hydrogen peroxide [9] has been used as a power source for propellant tank pumps in rockets like the German WWII V-2 and the American Redstone. [10] The hydrogen peroxide is passed through a platinum catalyst mesh, [ 9 ] or comes in contact with manganese dioxide impregnated ceramic beads, or Z-Stoff permanganate solution is co-injected, which ...
It is far less toxic than hydrazine and has a much lower boiling point, though it can be liquified at room temperature under pressure. Like hydrazine it has a positive enthalpy of formation that makes it both potentially unstable and a viable monopropellant. It can be decomposed with a catalyst to produce a hot mixture of nitrogen and oxygen. [1]
Carl Wilhelm Scheele (German:, Swedish: [ˈɧêːlɛ]; 9 December 1742 – 21 May 1786 [2]) was a German Swedish [3] pharmaceutical chemist.. Scheele discovered oxygen (although Joseph Priestley published his findings first), and identified molybdenum, tungsten, barium, nitrogen, and chlorine, among others.