Search results
Results from the WOW.Com Content Network
Dimethyldichlorosilane is a tetrahedral organosilicon compound with the formula Si(CH 3) 2 Cl 2. At room temperature it is a colorless liquid that readily reacts with water to form both linear and cyclic Si-O chains. Dimethyldichlorosilane is made on an industrial scale as the principal precursor to dimethylsilicone and polysilane compounds.
Trimethylsilyl groups on a molecule have a tendency to make it more volatile, often making the compounds more amenable to analysis by gas chromatography or mass spectrometry. An example of such trimethylsilylation is mentioned in the Brassicasterol article. Such derivatizations are often done on a small scale in special vials.
The chemical formula of PDMS is CH 3 [Si(CH 3) 2 O] n Si(CH 3) 3, where n is the number of repeating monomer [Si(CH 3) 2 O] units. [4] Industrial synthesis can begin from dimethyldichlorosilane and water by the following net reaction: n Si(CH 3) 2 Cl 2 + (n+1) H 2 O → HO[Si(CH 3) 2 O] n H + 2n HCl. The polymerization reaction evolves ...
Charge carrier density, also known as carrier concentration, denotes the number of charge carriers per volume. In SI units, it is measured in m −3. As with any density, in principle it can depend on position. However, usually carrier concentration is given as a single number, and represents the average carrier density over the whole material.
2 CH 3 Cl + Si → (CH 3) 4−n SiCl n + other products While this reaction is the standard in industrial silicone production and is nearly identical to the first direct synthesis of methyltrichlorosilane, the overall process is inefficient with respect to methyltrichlorosilane. [ 2 ]
The SI unit of kilogram per cubic metre (kg/m 3) and the cgs unit of gram per cubic centimetre (g/cm 3) are probably the most commonly used units for density. One g/cm 3 is equal to 1000 kg/m 3 . One cubic centimetre (abbreviation cc) is equal to one millilitre.
Tetramethylsilane is the accepted internal standard for calibrating chemical shift for 1 H, 13 C and 29 Si NMR spectroscopy in organic solvents (where TMS is soluble). In water, where it is not soluble, sodium salts of DSS, 2,2-dimethyl-2-silapentane-5-sulfonate, are used instead. Because of its high volatility, TMS can easily be evaporated ...
Stock and Somieski completed the hydrolysis of dichlorosilane by putting the solution of H 2 SiCl 2 in benzene in brief contact with a large excess of water. [3] [5] A large-scale hydrolysis was done in a mixed ether/alkane solvent system at 0 °C, which gave a mixture of volatile and nonvolatile [H 2 SiO] n.