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The hydride adds to an electrophilic center, typically unsaturated carbon. Hydrides such as sodium hydride and potassium hydride are used as strong bases in organic synthesis. The hydride reacts with the weak Bronsted acid releasing H 2. Hydrides such as calcium hydride are used as desiccants, i.e. drying agents, to remove trace water from ...
In chemistry, an acid–base reaction is a chemical reaction that occurs between an acid and a base.It can be used to determine pH via titration.Several theoretical frameworks provide alternative conceptions of the reaction mechanisms and their application in solving related problems; these are called the acid–base theories, for example, Brønsted–Lowry acid–base theory.
Bases and acids are seen as chemical opposites because the effect of an acid is to increase the hydronium (H 3 O +) concentration in water, whereas bases reduce this concentration. A reaction between aqueous solutions of an acid and a base is called neutralization , producing a solution of water and a salt in which the salt separates into its ...
The E and C parameters refer, respectively, to the electrostatic and covalent contributions to the strength of the bonds that the acid and base will form. The equation is -ΔH = E A E B + C A C B + W. The W term represents a constant energy contribution for acid–base reaction such as the cleavage of a dimeric acid or base. The equation ...
Another possibility is the molecular autoionization reaction between two water molecules, in which one water molecule acts as an acid and another as a base. H 2 O + H 2 O ⇌ H 3 O + + HO −. The bicarbonate ion, HCO − 3, is amphoteric as it can act as either an acid or a base: As an acid, losing a proton: HCO − 3 + OH − ⇌ CO 2− 3 ...
KH reacts with water according to the reaction: KH + H 2 O → KOH + H 2. As a superbase, potassium hydride is more basic than sodium hydride. It is used to deprotonate certain carbonyl compounds to give enolates. It also deprotonates amines to give the corresponding amides of the type KNHR and KNR 2. [6]
An example of a weak base is ammonia. It does not contain hydroxide ions, but it reacts with water to produce ammonium ions and hydroxide ions. [4] The position of equilibrium varies from base to base when a weak base reacts with water. The further to the left it is, the weaker the base. [5]
Animation of a strong acid–strong base neutralization titration (using phenolphthalein). The equivalence point is marked in red. In chemistry, neutralization or neutralisation (see spelling differences) is a chemical reaction in which acid and a base react with an equivalent quantity of each other. In a reaction in water, neutralization ...
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