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Phosphorus pentabromide is a reactive, yellow solid of formula P Br 5, which has the structure [PBr 4] + Br − (tetrabromophosphonium bromide) in the solid state but in the vapor phase is completely dissociated to PBr 3 and Br 2.
Phosphorus pentachloride, phosphorus pentabromide, and phosphorus heptabromide are ionic in the solid and liquid states; PCl 5 is formulated as PCl 4 + PCl 6 –, but in contrast, PBr 5 is formulated as PBr 4 + Br −, and PBr 7 is formulated as PBr 4 + Br 3 −. They are widely used as chlorinating and brominating agents in organic chemistry.
formula system space group unit cell Å volume density comment ref Ca 2 PBr : cubic I 4 3d: a=5.96 Z=2 red brown [1]Ca 2 PBr : hexagonal R 3 m: a=4.23 c=20.9 Z=3 [1]Cu 12 P 20 Br 10: triclinic
In a solid, constituent particles (ions, atoms, or molecules) are closely packed together. The forces between particles are so strong that the particles cannot move freely but can only vibrate. As a result, a solid has a stable, definite shape, and a definite volume. Solids can only change their shape by an outside force, as when broken or cut.
A physical change involves a change in physical properties. Examples of physical properties include melting, transition to a gas, change of strength, change of durability, changes to crystal form, textural change, shape, size, color, volume and density. An example of a physical change is the process of tempering steel to
A large molecule with an ionized group is technically an ion, but its behavior may be largely the result of non-ionic interactions. For example, sodium stearate (the main constituent of traditional soaps) consists entirely of ions, yet it is a soft material quite unlike a typical ionic solid. There is a continuum between ionic solids and ...
Melting, or fusion, is a physical process that results in the phase transition of a substance from a solid to a liquid. This occurs when the internal energy of the solid increases, typically by the application of heat or pressure , which increases the substance's temperature to the melting point .
Phase transitions (phase changes) that help describe polymorphism include polymorphic transitions as well as melting and vaporization transitions. According to IUPAC, a polymorphic transition is "A reversible transition of a solid crystalline phase at a certain temperature and pressure (the inversion point) to another phase of the same chemical composition with a different crystal structure."