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Each orbital in an atom is characterized by a set of values of three quantum numbers n, ℓ, and m ℓ, which respectively correspond to electron's energy, its orbital angular momentum, and its orbital angular momentum projected along a chosen axis (magnetic quantum number). The orbitals with a well-defined magnetic quantum number are generally ...
The azimuthal quantum number can also denote the number of angular nodes present in an orbital. For example, for p orbitals, ℓ = 1 and thus the amount of angular nodes in a p orbital is 1. Magnetic quantum number
If an electron is in one of the 2p orbitals, rotating the system will generally move it into a different 2p orbital (usually it will wind up in a quantum superposition of all three basis states, m = +1, 0, −1). Similarly, if an electron is in one of the 4d orbitals, rotating the system will move it into a different 4d orbital.
Quantum orbital motion involves the quantum mechanical motion of rigid particles (such as electrons) about some other mass, or about themselves.In classical mechanics, an object's orbital motion is characterized by its orbital angular momentum (the angular momentum about the axis of rotation) and spin angular momentum, which is the object's angular momentum about its own center of mass.
Other magnetic quantum numbers are similarly defined, such as m j for the z-axis component the total electronic angular momentum j, [1] and m I for the nuclear spin I. [2] Magnetic quantum numbers are capitalized to indicate totals for a system of particles, such as M L or m L for the total z-axis orbital angular momentum of all the electrons ...
A planar node can be described in an electromagnetic wave as the midpoint between crest and trough, which has zero magnitudes. In an s orbital, no nodes go through the nucleus, therefore the corresponding azimuthal quantum number ℓ takes the value of 0. In a p orbital, one node traverses the nucleus and therefore ℓ has the value of 1.
The spherical harmonics are eigenfunctions of the square of the orbital angular momentum = + (+) = . Laplace's spherical harmonics are the joint eigenfunctions of the square of the orbital angular momentum and the generator of rotations about the azimuthal axis: = =.
The classical definition of angular momentum is =.The quantum-mechanical counterparts of these objects share the same relationship: = where r is the quantum position operator, p is the quantum momentum operator, × is cross product, and L is the orbital angular momentum operator.