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In organic chemistry, the Myers deoxygenation reaction is an organic redox reaction that reduces an alcohol into an alkyl position by way of an arenesulfonyl hydrazine as a key intermediate. This name reaction is one of four discovered by Andrew Myers that are named after him; this reaction and the Myers allene synthesis reaction involve the ...
In organic chemistry, the Myers allene synthesis is a chemical reaction that converts a propargyl alcohol into an allene by way of an arenesulfonyl hydrazine as a key intermediate. [1] This name reaction is one of two discovered by Andrew Myers that are named after him; both this reaction and the Myers deoxygenation reaction involve the same ...
In stereochemistry, a chiral auxiliary is a stereogenic group or unit that is temporarily incorporated into an organic compound in order to control the stereochemical outcome of the synthesis. [ 1 ] [ 2 ] The chirality present in the auxiliary can bias the stereoselectivity of one or more subsequent reactions.
Reductive elimination is an elementary step in organometallic chemistry in which the oxidation state of the metal center decreases while forming a new covalent bond between two ligands. It is the microscopic reverse of oxidative addition, and is often the product-forming step in many catalytic processes. Since oxidative addition and reductive ...
Organic redox reactions: the Birch reduction. Organic reductions or organic oxidations or organic redox reactions are redox reactions that take place with organic compounds.In organic chemistry oxidations and reductions are different from ordinary redox reactions, because many reactions carry the name but do not actually involve electron transfer. [1]
The Schlenk line (also vacuum gas manifold) is a commonly used chemistry apparatus developed by Wilhelm Schlenk. [1] It consists of a dual manifold with several ports. [ 2 ] One manifold is connected to a source of purified inert gas , while the other is connected to a vacuum pump .
The Dowd-Beckwith ring expansion reaction is also capable of adding several carbons to a ring at a time, and is a useful tool for making large rings. [11] While it proceeds through an intermediate bicycle the final cyclization and ring opening take place within the same radical reaction . [ 12 ]
X-ray crystal structures and 11 B NMR spectroscopic analyses of the coordinated catalyst-borane complex 2 have provided support for this initial step. [ 5 ] [ 7 ] Subsequently, the endocyclic boron of the catalyst coordinates to the ketone at the sterically more accessible electron lone pair (i.e. the lone pair closer to the smaller substituent ...