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Hydrogen peroxide is a typical oxidant—for example, with dimethyl sulfide (S(CH 3) 2): [9] S(CH 3) 2 + H 2 O 2 → OS(CH 3) 2 + H 2 O OS(CH 3) 2 + H 2 O 2 → O 2 S(CH 3) 2 + H 2 O. In analogy to their easy alkylation, sulfides bind to metals to form thioether complexes. Consequently, Lewis acids do not decompose thioethers as they do ethers ...
Dimethyl sulfide has a characteristic odor commonly described as cabbage-like.It becomes highly disagreeable at even quite low concentrations. Some reports claim that DMS has a low olfactory threshold that varies from 0.02 to 0.1 ppm [clarification needed] between different persons, but it has been suggested that the odor attributed to dimethyl sulfide may in fact be due to disulfides ...
Thioether complexes feature pyramidal sulfur centers. Typical C-S-C angles are near 99° in both free thioethers and their complexes. The C-S distance in dimethylsulfide is 1.81 Å, which is also unaffected in its complexes. [5] The stereochemistry of thioether complexes have been extensively studied. [6]
The general structure of an ether. R and R' represent most organyl substituents.. In organic chemistry, ethers are a class of compounds that contain an ether group—a single oxygen atom bonded to two separate carbon atoms, each part of an organyl group (e.g., alkyl or aryl).
In organic chemistry, a sulfone is a organosulfur compound containing a sulfonyl (R−S(=O) 2 −R’) functional group attached to two carbon atoms. The central hexavalent sulfur atom is double-bonded to each of two oxygen atoms and has a single bond to each of two carbon atoms, usually in two separate hydrocarbon substituents .
Diethyl sulfide (British English: diethyl sulphide) is an organosulfur compound with the chemical formula (CH 3 CH 2) 2 S. It is a colorless, malodorous liquid. Although a common thioether, it has few applications.
Sulfur mustard (mustard gas) is an organosulfur compound (thioether) that was used as a chemical weapon in the First World War. 13–14: 217: 505-60-2: Ag 2 S: Silver sulfide is a component of silver tarnish. 21548-73-2: Na 2 S: Sodium sulfide, as the hydrate, is used in manufacture of kraft paper and as a precursor to organosulfur compounds ...
Dimethyl ether (DME; also known as methoxymethane) is the organic compound with the formula CH 3 OCH 3, (sometimes ambiguously simplified to C 2 H 6 O as it is an isomer of ethanol). The simplest ether , it is a colorless gas that is a useful precursor to other organic compounds and an aerosol propellant that is currently being demonstrated for ...