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A photoswitch is a type of molecule that can change its structural geometry and chemical properties upon irradiation with electromagnetic radiation.Although often used interchangeably with the term molecular machine, a switch does not perform work upon a change in its shape whereas a machine does. [1]
The first example of an artificial molecular machine (AMM) was reported in 1994, featuring a rotaxane with a ring and two different possible binding sites. In 2016 the Nobel Prize in Chemistry was awarded to Jean-Pierre Sauvage, Sir J. Fraser Stoddart, and Bernard L. Feringa for the design and synthesis of molecular machines.
Synthetic molecular motors are molecular machines capable of continuous directional rotation under an energy input. [2] Although the term "molecular motor" has traditionally referred to a naturally occurring protein that induces motion (via protein dynamics), some groups also use the term when referring to non-biological, non-peptide synthetic motors.
Many mechanically interlocked molecules have been studied to construct molecular machines. Because the molecules are linked by mechanical bonds instead of conventional covalent bonds, a component can move (shuttle) or rotate around the other parent component, which results in the large amount of freedom of mechanically interlocked molecules.
Molecular motors are natural (biological) or artificial molecular machines that are the essential agents of movement in living organisms. In general terms, a motor is a device that consumes energy in one form and converts it into motion or mechanical work ; for example, many protein -based molecular motors harness the chemical free energy ...
Broader exploitation of mechanosynthesis awaits more advanced technology for constructing molecular machine systems, with ribosome-like systems as an attractive early objective. Much of the excitement regarding advanced mechanosynthesis regards its potential use in assembly of molecular-scale devices. Such techniques appear to have many ...
[citation needed] Towards the future discipline of Systems chemistry, the development of a multistage chiral catalysts [30] which comprises an integrated supramolecular system that brings together molecular recognition, chirality transfer, catalysis, stereoelectronic control and enantio-selectivity while all these processes can be enabled or ...
ATP synthase is a molecular machine. The overall reaction catalyzed by ATP synthase is: ADP + P i + 2H + out ⇌ ATP + H 2 O + 2H + in; ATP synthase lies across a cellular membrane and forms an aperture that protons can cross from areas of high concentration to areas of low concentration, imparting energy for the synthesis of ATP.