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[1] [2] In physical and analytical chemistry, infrared spectroscopy (IR spectroscopy) is a technique used to identify chemical compounds based on the way infrared radiation is absorbed by the compound. The absorptions in this range do not apply only to bonds in organic molecules.
An IR spectrum can be visualized in a graph of infrared light absorbance (or transmittance) on the vertical axis vs. frequency, wavenumber or wavelength on the horizontal axis. Typical units of wavenumber used in IR spectra are reciprocal centimeters, with the symbol cm −1. Units of IR wavelength are commonly given in micrometers (formerly ...
These expressions are independent of Einstein coefficients. Absorption and emission often reach equilibrium inside dense, non-transparent materials, so such materials often emit thermal infrared of nearly blackbody intensity. Some of that radiation is internally reflected or scattered at a surface, producing emissivity less than 1.
The two forms have different dimensions and units: spectral irradiance of a frequency spectrum is measured in watts per square metre per hertz (W⋅m −2 ⋅Hz −1), while spectral irradiance of a wavelength spectrum is measured in watts per square metre per metre (W⋅m −3), or more commonly watts per square metre per nanometre (W⋅m −2 ...
By recording the attenuation of light for various wavelengths, an absorption spectrum can be obtained. In physics , absorption of electromagnetic radiation is how matter (typically electrons bound in atoms ) takes up a photon 's energy —and so transforms electromagnetic energy into internal energy of the absorber (for example, thermal energy ).
It is also common to employ interferometry to determine the spectrum—Fourier transform infrared spectroscopy is a widely used implementation of this technique. Two other issues that must be considered in setting up an absorption spectroscopy experiment include the optics used to direct the radiation and the means of holding or containing the ...
Infrared (IR; sometimes called infrared light) is electromagnetic radiation (EMR) with wavelengths longer than that of visible light but shorter than microwaves. The infrared spectral band begins with waves that are just longer than those of red light (the longest waves in the visible spectrum ), so IR is invisible to the human eye.
Infrared energy is emitted from a heated filament. By optically filtering the energy, the radiation spectrum is limited to the absorption band of the gas being measured. A detector measures the energy after the infrared energy has passed through the gas to be measured. This is compared to the energy at reference condition of no absorption.