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The all-cis isomer , a fully convex decagon, would have bond angles of 144°, which creates large amounts of angle strain relative to the ideal 120° in sp 2 atomic hybridization. Instead, the all- cis isomer adopts a planar boat-like conformation ( 2 ) to relieve the angle strain, [ 5 ] although it, too, is less stable than the next planar ...
Decene / d ɛ k iː n / is an organic compound with the chemical formula C 10 H 20. Decene contains a chain of ten carbon atoms with one double bond, making it an alkene. There are many isomers of decene depending on the position and geometry of the double bond. Dec-1-ene is the only isomer of industrial importance.
Cyclododecatrienes are cyclic trienes with the formula C 12 H 18.Four isomers are known for 1,5,9-cyclododecatriene. The trans,trans,cis-isomer is a precursor in the production of nylon-12.
Decalin occurs in cis and trans forms.The trans form is energetically more stable because of fewer steric interactions. cis-Decalin is a chiral molecule without a chiral center; it has a two-fold rotational symmetry axis, but no reflective symmetry.
The descriptors cis (Latin, on this side of) [2] and trans (Latin, over, beyond) [3] are used in various contexts for the description of chemical configurations: [4] [5] In organic structural chemistry , the configuration of a double bond can be described with cis and trans , in case it has a simple substitution pattern with only two residues.
Cyclodecene is a cycloalkene with a ten-membered ring, with two possible geometric isomers, denoted cis-cyclodecene and trans-cyclodecene, or (Z)-cyclodecene and (E)-cyclodecene. References [ edit ]
306-94-5 C 10 F 21 I: perfluorodecyl iodide: 423-62-1 C 10 H 4 Cl 8 O: oxychlordane: 26880-48-8 C 10 H 5 Cl 7: heptachlor: 76-44-8 C 10 H 5 Cl 7 O: heptachlor epoxide: 1024-57-3 C 10 H 5 Cu: copper phenylethynylacetylenide: 65792-84-9 C 10 H 5 F 15 O 2: ethyl perfluorooctanonate: 3108-24-5 C 10 H 6 Cl 2: dichloro naphthalene: 2050-69-3 C 10 H 6 ...
For instance, it can be prepared in almost 100% yield by converting the cis isomer to 1,2-epoxycyclooctane ("cyclooctene oxide") followed by reactions with lithium diphenylphosphide (LiPPh 2) and with methyl iodide CH 3 I. (Similar procedures can give cis,trans isomers of 1,4-cyclooctadiene and 1,5-cyclooctadiene). [2]