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2,6-Di-tert-butylphenol is an organic compound with the structural formula 2,6-((CH 3) 3 C) 2 C 6 H 3 OH.This colorless solid alkylated phenol and its derivatives are used industrially as UV stabilizers and antioxidants for hydrocarbon-based products ranging from petrochemicals to plastics. [1]
The chemical synthesis of BHT in industry has involved the reaction of p-cresol (4-methylphenol) with isobutylene (2-methylpropene), catalyzed by sulfuric acid: [11] CH 3 (C 6 H 4)OH + 2 CH 2 =C(CH 3) 2 → ((CH 3) 3 C) 2 CH 3 C 6 H 2 OH. Alternatively, BHT has been prepared from 2,6-di-tert-butylphenol by hydroxymethylation or aminomethylation ...
2,6-Di-tert-butylphenol This page was last edited on 7 September 2024, at 02:53 (UTC). Text is available under the Creative Commons Attribution-ShareAlike 4.0 ...
2,6‑Dialkylphenols (e.g. 2,6-dimethylphenol, 2,6-diisopropylphenol, 2,6-di-tert-butylphenol) — Also removed in DBU-catalyzed high-pressure methanolysis at room temperature. [84] Allyl esters — As with allyl ethers, also removed by diverse platinum complexes – connected with acid workup [85]
2-tert-Butylphenol is an intermediate in the industrial production of 2,6-di-tert-butylphenol, a common antioxidant. [2] Hydrogenation of 2-tert-butylphenol gives cis-2-tert-butylcyclohexanol, which when acetylated is a commercial fragrance. [2]
2,4-Di-tert-butylphenol (2,4-DTBP) is a white solid with a phenolic odour. It is primarily used as a raw material for the production of several commercially important antioxidants and phenolic benzotriazole -type UV absorbers .
This alkylation provides a means to separate 2,4-xylenol from 2,5-xylenol since 2,4-dimethyl-6-tert-butylphenol is insoluble in 10% NaOH but 2,5-dimethyl-6-tert-butylphenol is soluble. Subsequent to separation, the tert-butyl group can be removed in strong acid. [1]
[5] 2,4,6-tri-tert-butylphenol is also found as a by-product in the synthesis of the disubstitution products 2,4-DTBP and 2,6-DTBP, which are more widely used antioxidants. [2] Synthese von 2,4,6-Tri-tert-butylphenol mit Isobuten. A synthesis of 2,4,6-tri-tert-butylphenol has been described that is also suitable as a teaching experiment.