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For example, a wavenumber in inverse centimeters can be converted to a frequency expressed in the unit gigahertz by multiplying by 29.979 2458 cm/ns (the speed of light, in centimeters per nanosecond); [5] conversely, an electromagnetic wave at 29.9792458 GHz has a wavelength of 1 cm in free space.
The refractive index, , can be seen as the factor by which the speed and the wavelength of the radiation are reduced with respect to their vacuum values: the speed of light in a medium is v = c/n, and similarly the wavelength in that medium is λ = λ 0 /n, where λ 0 is the wavelength of that
In a dispersive medium, the phase speed itself depends upon the frequency of the wave, making the relationship between wavelength and frequency nonlinear. In the case of electromagnetic radiation—such as light—in free space, the phase speed is the speed of light, about 3 × 10 8 m/s.
A molecular vibration is a periodic motion of the atoms of a molecule relative to each other, such that the center of mass of the molecule remains unchanged. The typical vibrational frequencies range from less than 10 13 Hz to approximately 10 14 Hz, corresponding to wavenumbers of approximately 300 to 3000 cm −1 and wavelengths of approximately 30 to 3 μm.
As a wave, light is characterized by a velocity (the speed of light), wavelength, and frequency. As particles, light is a stream of photons . Each has an energy related to the frequency of the wave given by Planck's relation E = hf , where E is the energy of the photon, h is the Planck constant , 6.626 × 10 −34 J·s, and f is the frequency ...
The speed of light in vacuum, commonly denoted c, is a universal physical constant that is exactly equal to 299,792,458 metres per second (approximately 300,000 kilometres per second; 186,000 miles per second; 671 million miles per hour).
It is possible to make the effective speed of light dependent on wavelength by making light pass through a material which has a non-constant index of refraction, or by using light in a non-uniform medium such as a waveguide. In this case, the waveform will spread over time, such that a narrow pulse will become an extended pulse, i.e., be dispersed.
The speed of light in vacuum is defined to be exactly 299 792 458 m/s (approximately 186,282 miles per second). The fixed value of the speed of light in SI units results from the fact that the metre is now defined in terms of the speed of light. All forms of electromagnetic radiation move at exactly this same speed in vacuum.