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  2. Van der Waals constants (data page) - Wikipedia

    en.wikipedia.org/wiki/Van_der_Waals_constants...

    To convert from / to /, divide by 1000. a (L ... Benzene: 18.24 0.1193 Bromobenzene: 28.94 0.1539 ... Ethane: 5.562 0.0638 Ethanethiol: 11.39 0.08098

  3. Buchner ring expansion - Wikipedia

    en.wikipedia.org/wiki/Buchner_ring_expansion

    The reaction mechanism of a Buchner ring expansion begins with carbene formation from ethyl-diazoacetate generated initially through photochemical or thermal reactions with extrusion of nitrogen. carbene mechanism. The generated carbene adds to one of the double bonds of benzene to form the cyclopropane ring. carbene insertion

  4. Transalkylation - Wikipedia

    en.wikipedia.org/wiki/Transalkylation

    The reaction is used for the transfer of methyl and ethyl groups between benzene rings. This is of particular value in the petrochemical industry [1] to manufacture p-xylene, styrene, [2] and other aromatic compounds. Motivation for using transalkylation reactions is based on a difference in production and demand for benzene, toluene, and xylenes.

  5. Alkyne trimerisation - Wikipedia

    en.wikipedia.org/wiki/Alkyne_trimerisation

    An alkyne trimerisation is a [2+2+2] cycloaddition reaction in which three alkyne units (C≡C) react to form a benzene ring. The reaction requires a metal catalyst. The process is of historic interest as well as being applicable to organic synthesis. [1] Being a cycloaddition reaction, it has high atom economy.

  6. Catalytic reforming - Wikipedia

    en.wikipedia.org/wiki/Catalytic_reforming

    A side reaction is hydrogenolysis, which produces light hydrocarbons of lower value, such as methane, ethane, propane and butanes. Continuous Catalytic reforming (CCR) unit In addition to a gasoline blending stock, reformate is the main source of aromatic bulk chemicals such as benzene , toluene , xylene and ethylbenzene , which have diverse ...

  7. Wacker process - Wikipedia

    en.wikipedia.org/wiki/Wacker_process

    This net reaction can also be described as follows: [PdCl 4] 2 − + C 2 H 4 + H 2 O → CH 3 CHO + Pd + 2 HCl + 2 Cl −. This conversion is followed by reactions that regenerate the Pd(II) catalyst: Pd + 2 CuCl 2 + 2 Cl − → [PdCl 4] 2− + 2 CuCl 2 CuCl + ⁠ 1 / 2 ⁠ O 2 + 2 HCl → 2 CuCl 2 + H 2 O. Only the alkene and oxygen are consumed.

  8. Benzene - Wikipedia

    en.wikipedia.org/wiki/Benzene

    Benzene is a natural constituent of petroleum and is one of the elementary petrochemicals. Due to the cyclic continuous pi bonds between the carbon atoms, benzene is classed as an aromatic hydrocarbon. Benzene is a colorless and highly flammable liquid with a sweet smell, and is partially responsible for the aroma of gasoline.

  9. Ethylbenzene - Wikipedia

    en.wikipedia.org/wiki/Ethylbenzene

    Ethylbenzene is an organic compound with the formula C 6 H 5 CH 2 CH 3.It is a highly flammable, colorless liquid with an odor similar to that of gasoline.This monocyclic aromatic hydrocarbon is important in the petrochemical industry as a reaction intermediate in the production of styrene, the precursor to polystyrene, a common plastic material.