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Ammonia solution, also known as ammonia water, ammonium hydroxide, ammoniacal liquor, ammonia liquor, aqua ammonia, aqueous ammonia, or (inaccurately) ammonia, is a solution of ammonia in water. It can be denoted by the symbols NH 3 (aq). Although the name ammonium hydroxide suggests a salt with the composition [NH + 4][OH −
As a result, more water is forced into the container from another inlet creating a fountain effect. The demonstration introduces concepts like solubility and the gas laws at entry level. An ammonia fountain demonstration. A different gas of comparable solubility in water, such as hydrogen chloride, can be used instead of ammonia. [2]
The reaction between a ketone and ammonia results in an imine and byproduct water. This reaction is water sensitive and thus drying agents such as aluminum chloride or a Dean–Stark apparatus must be employed to remove water. The resulting imine will react and decompose back into the ketone and the ammonia when in the presence of water.
Assuming H 2 densities of 10 5 and [NH 2]/[H 2] ratio of 10 −7, this reaction proceeds at a rate of 2.2 × 10 −12, more than three orders of magnitude slower than the primary reaction above. Some of the other possible formation reactions are: H − + [NH 4] + → NH 3 + H 2 [PNH 3] + + e − → P + NH 3
As of 2018, the Haber process produces 230 million tonnes of anhydrous ammonia per year. [69] The ammonia is used mainly as a nitrogen fertilizer as ammonia itself, in the form of ammonium nitrate, and as urea. The Haber process consumes 3–5% of the world's natural gas production (around 1–2% of the world's energy supply).
Alternatively the reaction can be carried out with lead cyanate and ammonia. [4] The actual reaction taking place is a double displacement reaction to form ammonium cyanate: Pb(OCN) 2 + 2 NH 3 + 2 H 2 O → Pb(OH) 2 + 2NH 4 (OCN) Ammonium cyanate decomposes to ammonia and cyanic acid which in turn react to produce urea: NH 4 (OCN) → NH 3 ...
The classic example of a dehydration reaction is the Fischer esterification, which involves treating a carboxylic acid with an alcohol to give an ester RCO 2 H + R′OH ⇌ RCO 2 R′ + H 2 O. Often such reactions require the presence of a dehydrating agent, i.e. a substance that reacts with water.
2), and water (H 2 O). A reductant, typically anhydrous ammonia (NH 3), aqueous ammonia (NH 4 OH), or a urea (CO(NH 2) 2) solution, is added to a stream of flue or exhaust gas and is reacted onto a catalyst. As the reaction drives toward completion, nitrogen (N 2), and carbon dioxide (CO 2), in the case of urea use, are produced. Selective ...