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  2. trans-Cyclooctene - Wikipedia

    en.wikipedia.org/wiki/Trans-Cyclooctene

    trans-Cyclooctene is a cyclic hydrocarbon with the formula [–(CH 2) 6 CH=CH–], where the two C–C single bonds adjacent to the double bond are on opposite sides of the latter's plane. It is a colorless liquid with a disagreeable odor. Cyclooctene is notable as the smallest cycloalkene that is readily isolated as its trans-isomer.

  3. Cyclooctene - Wikipedia

    en.wikipedia.org/wiki/Cyclooctene

    Cyclooctene is notable because it is the smallest cycloalkene that can exist stably as either the cis or trans stereoisomer, with cis-cyclooctene being the most common. Theoretical analysis implies a total of 16 conformational and configurational isomers, all chiral, forming 8 enantiomeric pairs. [ 1 ]

  4. Cycloalkene - Wikipedia

    en.wikipedia.org/wiki/Cycloalkene

    The most stable trans-isomers of 10 ring or greater cycloalkenes exhibit 4 irregularities from standard geometric norms. The first irregularity is twisted planes of substituents along the C=C. Using C=C as the stable axis, 2 substituents of 1 carbon can be visualized on the same plane, equally applied to the other carbon.

  5. Click chemistry - Wikipedia

    en.wikipedia.org/wiki/Click_chemistry

    Like the other reactions of the trans-cyclooctene, ring strain release is a driving force for this reaction. Thus, three-membered and four-membered cycloalkenes, due to their high ring strain, make ideal alkene substrates.

  6. Bioorthogonal chemistry - Wikipedia

    en.wikipedia.org/wiki/Bioorthogonal_chemistry

    E-cyclooctene has a highly twisted double bond resulting in a strain energy of 17.9 kcal/mol. [37] As such, the highly strained trans-cyclooctene is used as a reactive dienophile. The diene is a 3,6-diaryl-s-tetrazine which has been substituted in order to resist immediate reaction with water.

  7. Hofmann elimination - Wikipedia

    en.wikipedia.org/wiki/Hofmann_elimination

    An example of a Hofmann elimination (not involving a contrast between a Zaitsev product and a Hofmann product) is the synthesis of trans-cyclooctene. [4] The trans isomer is selectively trapped as a complex with silver nitrate (in this diagram the trans form looks like a cis form, but see the trans-cyclooctene article for better images):

  8. Transition metal alkene complex - Wikipedia

    en.wikipedia.org/wiki/Transition_metal_alkene...

    Structure of (acac)Rh(C 2 H 4)(C 2 F 4), distances (red) in picometers. [3]The bonding between alkenes and transition metals is described by the Dewar–Chatt–Duncanson model, which involves donation of electrons in the pi-orbital on the alkene to empty orbitals on the metal.

  9. cis-Cyclooctene - Wikipedia

    en.wikipedia.org/wiki/Cis-Cyclooctene

    Cyclooctene undergoes ring-opening metathesis polymerization to give polyoctenamers, which are marketed under the name Vestenamer. [3] cis-Cyclooctene (COE) is a substrate known for quite selectively forming the epoxide, as compared to other cycloalkenes, e.g. cyclohexene. Low amounts of radical by-products are found only.