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A number of materials contract on heating within certain temperature ranges; this is usually called negative thermal expansion, rather than "thermal contraction".For example, the coefficient of thermal expansion of water drops to zero as it is cooled to 3.983 °C (39.169 °F) and then becomes negative below this temperature; this means that water has a maximum density at this temperature, and ...
As quoted from this source in an online version of: J.A. Dean (ed), Lange's Handbook of Chemistry (15th Edition), McGraw-Hill, 1999; Section 4; Table 4.1, Electronic Configuration and Properties of the Elements Touloukian, Y. S., Thermophysical Properties of Matter, Vol. 12, Thermal Expansion, Plenum, New York, 1975.
In thermal physics and thermodynamics, the heat capacity ratio, also known as the adiabatic index, the ratio of specific heats, or Laplace's coefficient, is the ratio of the heat capacity at constant pressure (C P) to heat capacity at constant volume (C V).
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Like other nickel/iron compositions, Invar is a solid solution; that is, it is a single-phase alloy.In one commercial grade called Invar 36 it consists of approximately 36% nickel and 64% iron, [4] has a melting point of 1427C, a density of 8.05 g/cm3 and a resistivity of 8.2 x 10-5 Ω·cm. [5] The invar range was described by Westinghouse scientists in 1961 as "30–45 atom per cent nickel".
C is the coefficient of thermal expansion of the metal that forms the tape; L is the length of the tape or length of the line measured. is the observed temperature of the tape at the time of measurement; is the standard temperature, when the tape is at the correct length, often 20 °C;
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Therefore, the sign of thermal expansion coefficient is determined by the sign of the third derivative of the potential. In multidimensional case the geometrical nonlinearity is also present, i.e. lattice vibrations are nonlinear even in the case of harmonic interatomic potential. This nonlinearity contributes to thermal expansion.