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It can be denoted by the symbols NH 3 (aq). Although the name ammonium hydroxide suggests a salt with the composition [NH + 4][OH −], it is impossible to isolate samples of NH 4 OH. The ions NH + 4 and OH − do not account for a significant fraction of the total amount of ammonia except in extremely dilute solutions. [6]
Walsh diagrams in conjunction with molecular orbital theory can also be used as a tool to predict reactivity. By generating a Walsh Diagram and then determining the HOMO/LUMO of that molecule, it can be determined how the molecule is likely to react. In the following example, the Lewis acidity of AH 3 molecules such as BH 3 and CH 3 + is predicted.
Amines can be formed by the reaction of ammonia with alkyl halides or, more commonly, with alcohols: CH 3 OH + NH 3 → CH 3 NH 2 + H 2 O. Its ring-opening reaction with ethylene oxide give ethanolamine, diethanolamine, and triethanolamine. Amides can be prepared by the reaction of ammonia with carboxylic acid and their derivatives.
In chemistry, two versions of a molecule, one a "mirror image" of the other, are called enantiomers if they are not "superposable" (the correct technical term, though the term "superimposable" is also used) on each other. That is an example of chirality. In general, an object and its mirror image are called enantiomorphs.
The hydrogen atoms in the ammonium ion can be substituted with an alkyl group or some other organic group to form a substituted ammonium ion (IUPAC nomenclature: aminium ion). Depending on the number of organic groups, the ammonium cation is called a primary, secondary, tertiary, or quaternary. Except the quaternary ammonium cations, the ...
Molecular geometries can be specified in terms of 'bond lengths', 'bond angles' and 'torsional angles'. The bond length is defined to be the average distance between the nuclei of two atoms bonded together in any given molecule. A bond angle is the angle formed between three atoms across at least two bonds.
Comparison of several types of graphical projection, including elevation and plan views. To render each such picture, a ray of sight (also called a projection line, projection ray or line of sight) towards the object is chosen, which determines on the object various points of interest (for instance, the points that are visible when looking at the object along the ray of sight); those points of ...
Some of the major features of phase diagrams include congruent points, where a solid phase transforms directly into a liquid. There is also the peritectoid, a point where two solid phases combine into one solid phase during cooling. The inverse of this, when one solid phase transforms into two solid phases during cooling, is called the eutectoid.