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It forms the acetylacetonate anion C 5 H 7 O − 2 (commonly abbreviated acac −): C 5 H 8 O 2 ⇌ C 5 H 7 O − 2 + H + The structure of the acetylacetonate anion (acac −) In the acetylacetonate anion, both C-O bonds are equivalent. Both C-C central bonds are equivalent as well, with one hydrogen atom bonded to the central carbon atom (the ...
CAS Number. 600-14-6 ... Acetylpropionyl, also known as acetyl propionyl or 2,3-pentanedione, [1] is an organic compound, specifically a diketone. [2]
Acetylacetone (2,4-pentanedione) Acetylpropionyl (2,3-pentanedione) See also. C 5 H 8 O 2; Cyclopentanedione This page was last edited on 15 March ...
In 1,3-diketones, such as acetylacetone (2,4-pentanedione), the enol form is favored. The acid-catalyzed conversion of an enol to the keto form proceeds by proton transfer from O to carbon. The process does not occur intramolecularly, but requires participation of solvent or other mediators.
2,3,4-Pentanetrione appears as an orangy-red oil. [1] The more intense colour is due to the greater conjugation of double bonds, and potential resonance. [5] The type of colour centre is called a dependent chromophore, as when there are fewer C=O groups the colour is less intense or absent.
1,3-Cyclopentanedione is an organic compound with the formula (CH 2) 3 (CO) 2. It is one of two isomeric cyclopentanediones, the other being 1,2-cyclopentanedione. The enol is predicted to be about 1-3 kcal/mol more stable than the diketo form. [1] The enol structure has been confirmed by X-ray crystallography. [2]
Pauling's second rule is that the value of the first pK a for acids of the formula XO m (OH) n depends primarily on the number of oxo groups m, and is approximately independent of the number of hydroxy groups n, and also of the central atom X. Approximate values of pK a are 8 for m = 0, 2 for m = 1, −3 for m = 2 and < −10 for m = 3. [28]
More common is the dimethyl derivative 2,4-Me 2 C 5 H 5. Additionally, many pentadienyl ligands are cyclic, being derived from the addition of hydride to η 6 -arene complexes or hydride abstraction from cyclohexadiene complexes.