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2,2-Dimethylbutane, trivially known as neohexane at William Odling's 1876 suggestion, [4] is an organic compound with formula C 6 H 14 or (H 3 C-) 3-C-CH 2-CH 3. It is therefore an alkane , indeed the most compact and branched of the hexane isomers — the only one with a quaternary carbon and a butane (C 4 ) backbone.
In Figure 6, 2-chloro-2,3-dimethylbutane is stabilized through hyperconjugation from electron donation from σ C-H into σ* C-Cl, but both C–H and C–Cl bonds are weakened. A molecular orbital diagram shows that the mixing of σ C–H and σ* C–Cl in 2-chloro-2,3-dimethylbutane lowers the energy of both the orbitals (Figure 7).
Download as PDF; Printable version; ... Preferred IUPAC name. 1-Chloro-2-methylpropane. Identifiers CAS Number. 513-36-0 ...
The following other wikis use this file: Usage on de.wikipedia.org 2-Chlor-2-methylbutan; Usage on eo.wikipedia.org T-Amila klorido; Usage on fa.wikipedia.org
Download as PDF; Printable version; In other projects ... Dimethylbutane (DMB) may refer to: 2,2-Dimethylbutane; 2,3-Dimethylbutane ; See also ... This page was last ...
Download as PDF; Printable version; ... Names Preferred IUPAC name ... -1-Chlorobut-2-ene. Other names 1-Chloro-2-butene, 1-chlorobut-2-ene, 2-butenyl chloride, gamma ...
The gauche effect is very sensitive to solvent effects, due to the large difference in polarity between the two conformers.For example, 2,3-dinitro-2,3-dimethylbutane, which in the solid state exists only in the gauche conformation, prefers the gauche conformer in benzene solution by a ratio of 79:21, but in carbon tetrachloride, it prefers the anti conformer by a ratio of 58:42. [9]
3D structure A Newman projection is a drawing that helps visualize the 3-dimensional structure of a molecule. [ 1 ] This projection most commonly sights down a carbon-carbon bond, making it a very useful way to visualize the stereochemistry of alkanes.