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Sulfur oxide refers to many types of sulfur and oxygen containing compounds such as SO, SO 2, SO 3, S 7 O 2, S 6 O 2, S 2 O 2, etc. Sulfur oxide (SO x) refers to one or more of the following: Lower sulfur oxides (S n O, S 7 O 2 and S 6 O 2) Sulfur monoxide (SO) and its dimer, Disulfur dioxide (S 2 O 2) Sulfur dioxide (SO 2) Sulfur trioxide (SO 3)
Sulfur polycations, S 8 2+, S 4 2+ and S 16 2+ are produced when sulfur is reacted with oxidising agents in a strongly acidic solution. [1] The colored solutions produced by dissolving sulfur in oleum were first reported as early as 1804 by C.F. Bucholz, but the cause of the color and the structure of the polycations involved was only ...
Thionyl tetrafluoride, also known as sulfur tetrafluoride oxide, is an inorganic compound with the formula S O F 4. It is a colorless gas. The shape of the molecule is a distorted trigonal bipyramid, with the oxygen found on the equator. The atoms on the equator have shorter bond lengths than the fluorine atoms on the axis.
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The S-S bond length is 188.4 pm, the S-O bond is 146.5 pm and the SSO angle is 117.88°. The two dipole moment components are μ a = 0.875 D and μ b = 1.18 D. [3] This species decomposes to give a polymeric sulfur oxides ("PSO's") with the approximate formula [S 3 O] n. PSO's decompose at room temperature to elemental sulfur and SO 2.
Higher sulfur oxides are a group of chemical compounds with the formula SO 3+x where x lies between 0 and 1. They contain peroxo (O−O) groups, and the oxidation state of sulfur is +6 as in SO 3 . Monomeric SO 4 can be isolated at low temperatures (below 78 K) following the reaction of SO 3 and atomic oxygen or photolysis of SO 3 – ozone ...
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