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Competition experiment between SN2 and E2. With ethyl bromide, the reaction product is predominantly the substitution product. As steric hindrance around the electrophilic center increases, as with isobutyl bromide, substitution is disfavored and elimination is the predominant reaction. Other factors favoring elimination are the strength of the ...
Pyridines are especially reactive when substituted in the aromatic ortho position or aromatic para position because then the negative charge is effectively delocalized at the nitrogen position. One classic reaction is the Chichibabin reaction ( Aleksei Chichibabin , 1914) in which pyridine is reacted with an alkali-metal amide such as sodium ...
Reactive nitrogen ("Nr"), also known as fixed nitrogen [1], refers to all forms of nitrogen present in the environment except for molecular nitrogen (N 2 ). [ 2 ] While nitrogen is an essential element for life on Earth, molecular nitrogen is comparatively unreactive, and must be converted to other chemical forms via nitrogen fixation before it ...
Nevertheless, nitrogen gas does react with the alkali metal lithium to form compound lithium nitride (Li 3 N), even under ordinary conditions. Under high pressures and temperatures and with the right catalysts, nitrogen becomes more reactive; the Haber process uses such conditions to produce ammonia from atmospheric nitrogen.
In organometallic chemistry, organolithium reagents are chemical compounds that contain carbon–lithium (C–Li) bonds.These reagents are important in organic synthesis, and are frequently used to transfer the organic group or the lithium atom to the substrates in synthetic steps, through nucleophilic addition or simple deprotonation. [1]
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In this type of substitution reaction, one group of the substrate participates initially in the reaction and thereby affects the reaction. A classic example of NGP is the reaction of a sulfur or nitrogen mustard with a nucleophile, the rate of reaction is much higher for the sulfur mustard and a nucleophile than it would be for a primary or secondary alkyl chloride without a heteroatom.