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PbCl 2 is sparingly soluble in water, solubility product K sp = 1.7 × 10 −5 at 20 °C. It is one of only 5 commonly water-insoluble chlorides, the other 4 being thallium(I) chloride , silver chloride (AgCl) with K sp = 1.8 × 10 −10 , copper(I) chloride (CuCl) with K sp = 1.72 × 10 −7 and mercury(I) chloride (Hg 2 Cl 2 ) with K sp = 1.3 ...
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
Substance Formula 0 °C 10 °C 20 °C 30 °C 40 °C 50 °C 60 °C 70 °C 80 °C 90 °C 100 °C Barium acetate: Ba(C 2 H 3 O 2) 2: 58.8: 62: 72: 75: 78.5: 77: 75
The compounds are almost insoluble in water, weak acids, and (NH 4) 2 S/(NH 4) 2 S 2 solution is the key for separation of lead from analytical groups I to III elements, tin, arsenic, and antimony. The compounds dissolve in nitric and hydrochloric acids, to give elemental sulfur and hydrogen sulfide, respectively. [ 7 ]
Very soluble <1 calcium nitrate: 158.7 0.63 Freely soluble 1 to 10 calcium chloride: 65 1.54 Soluble 10 to 30 sodium oxalate: 3.9 26 Sparingly soluble 30 to 100 Slightly soluble 100 to 1000 calcium sulfate: 0.21 490 Very slightly soluble 1000 to 10,000 dicalcium phosphate: 0.02 5000 Practically insoluble or insoluble ≥ 10,000 barium sulfate ...
Lead tetrachloride can be made by reacting lead(II) chloride PbCl 2, and hydrochloric acid HCl, in the presence of chlorine gas (Cl 2), [5] leading to the formation of chloroplumbic acid H 2 PbCl 6.
Lead(II) fluoride can be prepared by treating lead(II) hydroxide or lead(II) carbonate with hydrofluoric acid: [3]. Pb(OH) 2 + 2 HF → PbF 2 + 2 H 2 O Alternatively, it is precipitated by adding hydrofluoric acid to a lead(II) salt solution, or by adding a fluoride salt to a lead salt, such as potassium fluoride to a lead(II) nitrate solution, [4]
This process exploits its low solubility in water - only 0.455 g dissolves in 100 g of water at 0 °C. It is about ten times more soluble in boiling water. [5] PbBr 2 has the same crystal structure as lead chloride – they are isomorphous.