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A homologous series is a group of compounds that differ by a constant unit, generally a methylene (−CH 2 −) group. The reactants undergo a homologation when the number of a repeated structural unit in the molecules is increased. The most common homologation reactions increase the number of methylene (−CH 2 −) units in saturated chain ...
The name "homologous series" is also often used for any collection of compounds that have similar structures or include the same functional group, such as the general alkanes (straight and branched), the alkenes (olefins), the carbohydrates, etc. However, if the members cannot be arranged in a linear order by a single parameter, the collection ...
More complex alkenes may be named with the E–Z notation for molecules with three or four different substituents (side groups). For example, of the isomers of butene , the two methyl groups of ( Z )-but-2 -ene (a.k.a. cis -2-butene) appear on the same side of the double bond, and in ( E )-but-2-ene (a.k.a. trans -2-butene) the methyl groups ...
Alkyl groups form homologous series. The simplest series have the general formula −C n H 2n+1. Alkyls include methyl, (−CH 3), ethyl (−C 2 H 5), propyl (−C 3 H 7), butyl (−C 4 H 9), pentyl (−C 5 H 11), and so on. Alkyl groups that contain one ring have the formula −C n H 2n−1, e.g. cyclopropyl and cyclohexyl.
The same is true when an alkene reacts with water in an additional reaction to form an alcohol that involves carbocation formation. The hydroxyl group (OH) bonds to the carbon that has the greater number of carbon-carbon bonds, while the hydrogen bonds to the carbon on the other end of the double bond, that has more carbon–hydrogen bonds.
For example, sugar dissolves in water because both share the hydroxyl functional group (−OH) and hydroxyls interact strongly with each other. Plus, when functional groups are more electronegative than atoms they attach to, the functional groups will become polar, and the otherwise nonpolar molecules containing these functional groups become ...
There are two types of alpha-olefins, branched and linear (or normal). The chemical properties of branched alpha-olefins with a branch at either the second (vinylidene) or the third carbon number are significantly different from the properties of linear alpha-olefins and those with branches on the fourth carbon number and further from the start of the chain.
The angle between the two H atoms is 121.5°, similar to the theoretically ideal angle formed in alkenes between sp 2 carbon atom and H substituents. [5] Ketenes are unstable and cannot be stored. In the absence of nucleophiles with which to react, ethenone dimerises to give β-lactone, a cyclic ester. If the ketene is disubstituted, the ...