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In the absence of LC 50 data on the poisonous (toxic) constituent substances, the mixture may be assigned a packing group and hazard zone based on simplified threshold toxicity tests. When these threshold tests are used, the most restrictive packing group and hazard zone must be determined and used for the transportation of the mixture.
The Emergency Response Guidebook: A Guidebook for First Responders During the Initial Phase of a Dangerous Goods/Hazardous Materials Transportation Incident (ERG) is used by emergency response personnel (such as firefighters, paramedics and police officers) in Canada, Mexico, and the United States when responding to a transportation emergency involving hazardous materials.
The GHS transport pictograms are the same as those recommended in the UN Recommendations on the Transport of Dangerous Goods, widely implemented in national regulations such as the U.S. Federal Hazardous Materials Transportation Act (49 U.S.C. 5101–5128) and D.O.T. regulations at 49 C.F.R. 100–185.
"Dangerous goods" (also known as "hazardous materials" or "HAZMAT" in the United States) may be a pure chemical substance (e.g. TNT, nitroglycerin), mixtures (e.g. dynamite, gunpowder) or manufactured articles (e.g. ammunition, fireworks). The transport hazards that they pose are grouped into nine classes, which may be subdivided into divisions ...
The material is forbidden from being offered for transportation according to 49CFR 172.101 of this subchapter or 49CFR 173.21; The Associate Administrator for Hazardous Materials Safety has determined that the material does not present a hazard which is associated with a Division 5.2 material; or; The material meets one of the following conditions:
There are also long-standing European treaties such as ADR, [15] ADN and RID that regulate the transportation of hazardous materials by road, rail, river and inland waterways, following the guide of the UN model regulations. European law distinguishes clearly between the law of dangerous goods and the law of hazardous materials.
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