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The radius ratio rule defines a critical radius ratio for different crystal structures, based on their coordination geometry. [1] The idea is that the anions and cations can be treated as incompressible spheres, meaning the crystal structure can be seen as a kind of unequal sphere packing .
An octahedron may then form with a radius ratio greater than or equal to 0.414, but as the ratio rises above 0.732, a cubic geometry becomes more stable. This explains why Na + in NaCl with a radius ratio of 0.55 has octahedral coordination, whereas Cs + in CsCl with a radius ratio of 0.93 has cubic coordination.
For all these radius ratios a compact packing is known that achieves the maximum possible packing fraction (above that of uniformly-sized discs) for mixtures of discs with that radius ratio. [9] All nine have ratio-specific packings denser than the uniform hexagonal packing, as do some radius ratios without compact packings.
Each different crown shape will have an associated crown shape ratio of the measured maximum average crown spread to radius of the equivalent cylinder diameter. This value cannot be used directly but first must be converted to a unique Crown Form factor value. The formula for an equivalent cylinder may be expressed as follows:
r B is the radius of the B cation. r O is the radius of the anion (usually oxygen). In an ideal cubic perovskite structure, the lattice parameter (i.e., length) of the unit cell (a) can be calculated using the following equation: [ 1 ]
In applied sciences, the equivalent radius (or mean radius) is the radius of a circle or sphere with the same perimeter, area, or volume of a non-circular or non-spherical object. The equivalent diameter (or mean diameter ) ( D {\displaystyle D} ) is twice the equivalent radius.
More formulas of this nature can be given, as explained by Ramanujan's theory of elliptic functions to alternative bases. Perhaps the most notable hypergeometric inversions are the following two examples, involving the Ramanujan tau function τ {\displaystyle \tau } and the Fourier coefficients j {\displaystyle \mathrm {j} } of the J-invariant ...
Ionic radius, r ion, is the radius of a monatomic ion in an ionic crystal structure. Although neither atoms nor ions have sharp boundaries, they are treated as if they were hard spheres with radii such that the sum of ionic radii of the cation and anion gives the distance between the ions in a crystal lattice .