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Lead perchlorate trihydrate is produced by the reaction of lead(II) oxide, lead carbonate, or lead nitrate by perchloric acid: . Pb(NO 3) 2 + HClO 4 → Pb(ClO 4) 2 + HNO 3. The excess perchloric acid was removed by first heating the solution to 125 °C, then heating it under moist air at 160 °C to remove the perchloric acid by converting the acid to the dihydrate.
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
A perchlorate is a chemical compound containing the perchlorate ion, ClO − 4, the conjugate base of perchloric acid (ionic perchlorate).As counterions, there can be metal cations, quaternary ammonium cations or other ions, for example, nitronium cation (NO + 2).
Magnesium perchlorate is a powerful oxidizing agent, with the formula Mg(ClO 4) 2. The salt is also a superior drying agent for gas analysis. Magnesium perchlorate decomposes at 250 °C. [2] The heat of formation is -568.90 kJ/mol. [3] The enthalpy of solution is quite high, so reactions are done in large amounts of water to dilute it.
Calcium perchlorate is a strong inorganic oxidizing agent, enhancing the combustion of other substances that can potentially lead to explosion. The perchlorate ion, ClO − 4, has a highly symmetrical tetrahedral structure that is strongly stabilized in solution by its low electron-donating proton-accepting power and its relatively low polarizability.
Upon heating, perchlorate complexes yield oxides, evolving chlorine oxides in the process. For example, thermolysis of titanium perchlorate gives TiO 2, ClO 2, and O 2 The titanyl species TiO(ClO 4) 2 is an intermediate in this decomposition. [7] Ti(ClO 4) 4 → TiO 2 + 4ClO 2 + 3O 2 ΔH = +6 kcal/mol (25 kJ/mol)
It is then converted to the ammonium salt (NH 4) 2 PbCl 6 by adding ammonium chloride (NH 4 Cl). Finally, the solution is treated with concentrated sulfuric acid H 2 SO 4, to separate out lead tetrachloride. This series of reactions is conducted at 0 °C. The following equations illustrate the reaction: PbCl 2 + 2HCl + Cl 2 → H 2 PbCl 6
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