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The term is used almost exclusively to describe solutions and implies catalysis by organometallic compounds. Homogeneous catalysis is an established technology that continues to evolve. An illustrative major application is the production of acetic acid. Enzymes are examples of homogeneous catalysts. [2]
The process contrasts with homogeneous catalysis where the reagents, products and catalyst exist in the same phase. Phase distinguishes between not only solid, liquid, and gas components, but also immiscible mixtures (e.g., oil and water), or anywhere an interface is present.
The solution-phase intermediates are not necessarily distinguishable from those obtained during homogeneous cross-couplings – for example, a heterogeneous Pd-catalyzed Suzuki reaction still proceeds via oxidative addition of the electrophile by Pd(0), transmetallation of a boronate, and reductive elimination to give product and regenerate Pd ...
Homogeneity and heterogeneity; only ' b ' is homogeneous Homogeneity and heterogeneity are concepts relating to the uniformity of a substance, process or image.A homogeneous feature is uniform in composition or character (i.e., color, shape, size, weight, height, distribution, texture, language, income, disease, temperature, radioactivity, architectural design, etc.); one that is heterogeneous ...
Homogeneous metallocene catalysts, e.g., derived from or related to zirconocene dichloride introduced a level of microstructural control that was unavailable with heterogeneous systems. [2] Metallocene catalysts are homogeneous single-site systems, implying that a uniform catalyst is present in the solution. In contrast, commercially important ...
For example, during the electrolysis of water, the anode can oxidize water through a two electron process to hydrogen peroxide or a four electron process to oxygen. The presence of an electrocatalyst could facilitate either of the reaction pathways. [9] Types of electrocatalyst materials, including homogeneous and heterogeneous electrocatalysts.
Homogenization (from "homogeneous;" Greek, homogenes: homos, same + genos, kind) [5] is the process of converting two immiscible liquids (i.e. liquids that are not soluble, in all proportions, one in another) into an emulsion [6] (Mixture of two or more liquids that are generally immiscible).
A slurry reactor contains the catalyst in a powdered or granular form. [7] This reactor is typically used when one reactant is a gas and the other a liquid while the catalyst is a solid. The reactant gas is put through the liquid and dissolved. It then diffuses onto the catalyst surface.