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Chapman–Enskog theory provides a framework in which equations of hydrodynamics for a gas can be derived from the Boltzmann equation. The technique justifies the otherwise phenomenological constitutive relations appearing in hydrodynamical descriptions such as the Navier–Stokes equations .
The fusion of Chapman's and Enskog's theories later became known as the Chapman–Enskog method for solving the Boltzmann equation. In a 1939 book called The Mathematical Theory of Non-Uniform Gases, written by Chapman and Thomas Cowling and dedicated to David Enskog, the authors expanded this theory under the Chapman-Enskog designation.
The transfer of momentum between molecules is explicitly accounted for in Revised Enskog theory, which relaxes the requirement of a gas being dilute. The viscosity equation further presupposes that there is only one type of gas molecules, and that the gas molecules are perfect elastic and hard core particles of spherical shape.
At moderate densities (i.e. densities at which the gas has a non-negligible co-volume, but is still sufficiently dilute to be considered as gas-like rather than liquid-like) this simple relation no longer holds, and one must resort to Revised Enskog Theory. [9] Revised Enskog Theory predicts a diffusion coefficient that decreases somewhat more ...
The gas viscosity model of Chung et alios (1988) [5] is combination of the Chapman–Enskog(1964) kinetic theory of viscosity for dilute gases and the empirical expression of Neufeld et alios (1972) [6] for the reduced collision integral, but expanded empirical to handle polyatomic, polar and hydrogen bonding fluids over a wide temperature ...
The kinetic theory of gases allows accurate calculation of the temperature-variation of gaseous viscosity. The theoretical basis of the kinetic theory is given by the Boltzmann equation and Chapman–Enskog theory, which allow accurate statistical modeling of molecular trajectories.
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For instance, the particles are assumed to be pointlike, i.e. without having a finite size. There exists a generalization of the Boltzmann equation that is called the Enskog equation. [22] The collision term is modified in Enskog equations such that particles have a finite size, for example they can be modelled as spheres having a fixed radius.