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The simplest definition for a potential gradient F in one dimension is the following: [1] = = where ϕ(x) is some type of scalar potential and x is displacement (not distance) in the x direction, the subscripts label two different positions x 1, x 2, and potentials at those points, ϕ 1 = ϕ(x 1), ϕ 2 = ϕ(x 2).
The potential has units of energy per mass, e.g., J/kg in the MKS system. By convention, it is always negative where it is defined, and as x tends to infinity, it approaches zero. The gravitational field, and thus the acceleration of a small body in the space around the massive object, is the negative gradient of the gravitational potential ...
i.e., the external potential is the sum of electric potential, gravitational potential, etc. (where q and m are the charge and mass of the species, V ele and h are the electric potential [15] and height of the container, respectively, and g is the acceleration due to gravity). The internal chemical potential includes everything else besides the ...
If the force is not conservative, then defining a scalar potential is not possible, because taking different paths would lead to conflicting potential differences between the start and end points. Gravitational force is an example of a conservative force, while frictional force is an example of a non-conservative force.
Scalar potential is not determined by the vector field alone: indeed, the gradient of a function is unaffected if a constant is added to it. If V is defined in terms of the line integral, the ambiguity of V reflects the freedom in the choice of the reference point r 0 .
The gradient of F is then normal to the hypersurface. Similarly, an affine algebraic hypersurface may be defined by an equation F(x 1, ..., x n) = 0, where F is a polynomial. The gradient of F is zero at a singular point of the hypersurface (this is the definition of a singular point). At a non-singular point, it is a nonzero normal vector.
For two-body potentials this gradient reduces, thanks to the symmetry with respect to in the potential form, to straightforward differentiation with respect to the interatomic distances . However, for many-body potentials (three-body, four-body, etc.) the differentiation becomes considerably more complex [ 12 ] [ 13 ] since the potential may ...
For two pairwise interacting point particles, the gravitational potential energy is the work that an outside agent must do in order to quasi-statically bring the masses together (which is therefore, exactly opposite the work done by the gravitational field on the masses): = = where is the displacement vector of the mass, is gravitational force acting on it and denotes scalar product.