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Structural formula of the adipate dianion. The anionic (HO 2 C(CH 2) 4 CO 2 −) and dianionic (− O 2 C(CH 2) 4 CO 2 −) forms of adipic acid are referred to as adipates. An adipate compound is a carboxylate salt or ester of the acid. Some adipate salts are used as acidity regulators, including: Sodium adipate (E number E356) Potassium ...
The dry distillation of calcium acetate to give acetone was reported by Charles Friedel in 1858 [3] and until World War I ketonization was the premier commercial method for its production. [ 4 ] Ketonic decarboxylation of propanoic acid over a manganese(II) oxide catalyst in a tube furnace affords 3-pentanone .
A series of processes that involve carbonization. [2]Carbonization is a pyrolytic reaction, therefore, is considered a complex process in which many reactions take place concurrently such as dehydrogenation, condensation, hydrogen transfer and isomerization.
Carbonation is the chemical reaction of carbon dioxide to give carbonates, bicarbonates, and carbonic acid. [1] In chemistry, the term is sometimes used in place of carboxylation, which refers to the formation of carboxylic acids. In inorganic chemistry and geology, carbonation is common.
Fractional distillation in a laboratory makes use of common laboratory glassware and apparatuses, typically including a Bunsen burner, a round-bottomed flask and a condenser, as well as the single-purpose fractionating column. Fractional distillation. As an example, consider the distillation of a mixture of water and ethanol. Ethanol boils at ...
In the transesterification mechanism, the carbonyl carbon of the starting ester reacts to give a tetrahedral intermediate, which either reverts back to the starting material, or proceeds to the transesterified product (RCOOR 2). The various species exist in equilibrium, and the product distribution depends on the relative energies of the ...
Dry distillation is the heating of solid materials to produce gaseous products (which may condense into liquids or solids). The method may involve pyrolysis or thermolysis, or it may not (for instance, a simple mixture of ice and glass could be separated without breaking any chemical bonds, but organic matter contains a greater diversity of molecules, some of which are likely to break).
The reaction mechanism involves a two-stage radical process: electrochemical decarboxylation gives a radical intermediate, which combine to form a covalent bond. [2] As an example, electrolysis of acetic acid yields ethane and carbon dioxide: CH 3 COOH → CH 3 COO − → CH 3 COO· → CH 3 · + CO 2 2CH 3 · → CH 3 CH 3