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An amphiprotic molecule (or ion) can either donate or accept a proton, thus acting either as an acid or a base. Water , amino acids , hydrogencarbonate ion (or bicarbonate ion) HCO − 3 , dihydrogen phosphate ion H 2 PO − 4 , and hydrogensulfate ion (or bisulfate ion) HSO − 4 are common examples of amphiprotic species.
A species that can either accept or donate a proton is referred to as amphiprotic. An example is the H 2 O (water) molecule, which can gain a proton to form the hydronium ion, H 3 O +, or lose a proton, leaving the hydroxide ion, OH −. The relative ability of a molecule to give up a proton is measured by its pK a value.
The bicarbonate ion carries a negative one formal charge and is an amphiprotic species which has both acidic and basic properties. It is both the conjugate base of carbonic acid H 2 CO 3; and the conjugate acid of CO 2− 3, the carbonate ion, as shown by these equilibrium reactions: CO 2− 3 + 2 H 2 O ⇌ HCO −
An inorganic nonaqueous solvent is a solvent other than water, that is not an organic compound. These solvents are used in chemical research and industry for reactions that cannot occur in aqueous solutions or require a special environment. Inorganic nonaqueous solvents can be classified into two groups, protic solvents and aprotic solvents.
For example, anhydrous acetic acid (CH 3 COOH) as solvent is a weaker proton acceptor than water. Strong aqueous acids such as hydrochloric acid and perchloric acid are only partly dissociated in anhydrous acetic acid and their strengths are unequal; in fact perchloric acid is about 5000 times stronger than hydrochloric acid in this solvent. [ 3 ]
Some non-aqueous solvents can behave as acids. An acidic solvent will make dissolved substances more basic. For example, the compound CH 3 COOH is known as acetic acid since it behaves as an acid in water. However, it behaves as a base in liquid hydrogen fluoride, a much more acidic solvent. [13]
In general terms, any solvent that contains a labile H + is called a protic solvent. The molecules of such solvents readily donate protons (H +) to solutes, often via hydrogen bonding. Water is the most common protic solvent. Conversely, polar aprotic solvents cannot donate protons but still have the ability to dissolve many salts. [1] [2]
Hydrocarbon-based surfactants are an example group of amphiphilic compounds. Their polar region can be either ionic , or non-ionic. Some typical members of this group are: sodium dodecyl sulfate ( anionic ), benzalkonium chloride ( cationic ), cocamidopropyl betaine ( zwitterionic ), and 1-octanol (long-chain alcohol, non-ionic).