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The cooling produced in the Joule–Thomson expansion makes it a valuable tool in refrigeration. [ 8 ] [ 20 ] The effect is applied in the Linde technique as a standard process in the petrochemical industry , where the cooling effect is used to liquefy gases , and in many cryogenic applications (e.g. for the production of liquid oxygen ...
A cooling curve of naphthalene from liquid to solid. A cooling curve is a line graph that represents the change of phase of matter, typically from a gas to a solid or a liquid to a solid. The independent variable (X-axis) is time and the dependent variable (Y-axis) is temperature. [1] Below is an example of a cooling curve used in castings.
The Carnot cycle is a cycle composed of the totally reversible processes of isentropic compression and expansion and isothermal heat addition and rejection. The thermal efficiency of a Carnot cycle depends only on the absolute temperatures of the two reservoirs in which heat transfer takes place, and for a power cycle is:
The Brayton cycle, also known as the Joule cycle, is a thermodynamic cycle that describes the operation of certain heat engines that have air or some other gas as their working fluid. It is characterized by isentropic compression and expansion, and isobaric heat addition and rejection, though practical engines have adiabatic rather than ...
Here, work is entirely consumed by expansion against the surroundings. Of the total heat applied (709.3 kJ), the work performed (202.7 kJ) is about 28.6% of the supplied heat. Isobaric expansion of a gas pressurized to 2 atmospheres by a 10,333.2 kg mass. Like before, the gas doubles in volume and temperature while remaining at the same pressure.
The Hampson–Linde cycle differs from the Siemens cycle only in the expansion step. Whereas the Siemens cycle has the gas do external work to reduce its temperature, the Hampson–Linde cycle relies solely on the Joule–Thomson effect; this has the advantage that the cold side of the cooling apparatus needs no moving parts. [1]
Therefore, a quantity of work in such a system can be related almost directly to an equivalent quantity of heat in a cycle of two limbs. The first limb is an isochoric adiabatic work process increasing the system's internal energy ; the second, an isochoric and workless heat transfer returning the system to its original state.
The main feature of thermodynamic diagrams is the equivalence between the area in the diagram and energy. When air changes pressure and temperature during a process and prescribes a closed curve within the diagram the area enclosed by this curve is proportional to the energy which has been gained or released by the air.