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It is the acidic anhydride of chromic acid, and is sometimes marketed under the same name. [6] This compound is a dark-purple solid under anhydrous conditions and bright orange when wet. The substance dissolves in water accompanied by hydrolysis. [clarification needed] Millions of kilograms are produced annually, mainly for electroplating. [7]
Because of its considerable stability, chromia is a commonly used pigment. It was originally called viridian. It is used in paints, inks, and glasses. It is the colorant in "chrome green" and "institutional green." Chromium(III) oxide is a precursor to the magnetic pigment chromium dioxide, by the following reaction: [7] Cr 2 O 3 + 3 CrO 3 → ...
The Pourbaix diagram for chromium in pure water, perchloric acid, or sodium hydroxide [1] [2]. Chromium compounds are compounds containing the element chromium (Cr). Chromium is a member of group 6 of the transition metals.
Perbromic acid – HBrO 4 [161] Aluminium Bromide – AlBr 3 [11] Ammonium bromide – NH 4 Br [37] Boron tribromide – BBr 3 [146] Bromic acid – HBrO 3 [162] Bromine monoxide – Br 2 O [163] Bromine pentafluoride – BrF 5 [164] Bromine trifluoride – BrF 3 [165] Bromine monofluoride – BrF [166] Calcium bromide – CaBr 2 [167] Carbon ...
This kind of chromic acid may be used as a cleaning mixture for glass. Chromic acid may also refer to the molecular species, H 2 CrO 4 of which the trioxide is the anhydride. Chromic acid features chromium in an oxidation state of +6 (and a valence of VI or 6). It is a strong and corrosive oxidizing agent and a moderate carcinogen.
It is readily oxidized by the atmosphere. CrO is basic, while CrO 3 is acidic, and Cr 2 O 3 is amphoteric. [3] CrO occurs in the spectra of luminous red novae, which occur when two stars collide. It is not known why red novae are the only objects that feature this molecule; one possible explanation is an as-yet-unknown nucleosynthesis process. [4]
Structure of CrO(O 2) 2 (pyridine).Hydrogen atoms bonded to carbon atoms are omitted. Color code: Cr = gray, C= black, H = white, O= red, N = blue. Chromium(VI) oxide peroxide is formed by the addition of acidified hydrogen peroxide solutions to solutions of metal chromates or dichromates, such as sodium chromate or potassium dichromate.
The mechanism of this process likely depends on the acidity of the chromium reagent. Acidic reagents such as PCC may cause ionization and recombination of the chromate ester (path A), while the basic reagents (Collins) likely undergo direct allylic transposition via sigmatropic rearrangement (path B).